Cobalt-Catalyzed Divergent Aminofluorination and Diamination of Styrenes with N-Fluorosulfonamides.
作者： Ke-Yin Ye , Peng Guo , Jun-Fa Han , Jia-Bin Liao , Lin Chen
DOI: 10.1021/ACS.ORGLETT.1C01308
关键词:
摘要: A cobalt-catalyzed aminofluorination reaction of styrenes with N-fluorosulfonamides serving as both the amination and fluorination agents has been developed. The switch selectivity in this catalytic from to diamination could be easily achieved by addition 1.0 equiv PPh3. Both transformations tolerated a wide array substrates under mild conditions.
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