Process for the catalytic hydrogenation of liquid fatty acid triglycerides for simultaneous production of fatty alcohols and c3-diols

作者: Gerd Dr. Göbel , Norbert Bremus , Franz-Josef Dr. Carduck , Reinhard Eltner , Theo Dr. Fleckenstein

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摘要: Using a process for catalytic hydrogenation of liquid fatty acid triglycerides simultaneous production alcohols and C3-diols in the presence gaseous hydrogen catalysts at pressures from 50 to 300 bar temperatures 160 250 DEG , yield least 99% theory 1,2-propanediol 80% maximum paraffin content most 0.5% is achieved by carrying out reaction shell-and-tube reactor held under isothermal conditions means cooling or heating fluid, phase being passed over catalyst packings individual tubes as parallel current addition without remixing, selecting volume loading between 0.2 2.5 l feedstock per hour surface each tube 1.5 25 m cross-section adjusting parameters temperature pressure actual activity correspondingly. …

参考文章(2)
Pohl Dr Joachim, Juergen Prof Dr Falbe, Franz-Josef Dr Carduck, Theo Dr Fleckenstein, Process for direct hydrogenation of glyceric oils ,(1987)
Friedemann Dipl Ing Marschner, Theodor Dipl Chem Voeste, Hans Joachim Dipl Chem Schmidt, Verfahren zur kontinuierlichen herstellung von fettalkoholen ,(1978)