A comparison of valence level photoelectron cross sections for SF6, SeF6 and “F6” from 21 eV to 100 eV photon energy

作者: B.M. Addison-Jones , K.H. Tan , B.W. Yates , J.N. Cutler , G.M. Bancroft

DOI: 10.1016/0368-2048(89)80013-1

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摘要: Abstract High resolution photoelectron spectra of SF6 and SeF6 have been obtained in the 21 to 100 eV photon energy range using synchrotron radiation. All valence levels as well lower lying F2s, case Se, 3d were observed. Resulting experimental branching ratios partial cross sections then compared with those from MS-Xα calculations. This comparison provided following level ordering for SF6: 1t1g

参考文章(38)
M Sasanuma, E Ishiguro, H Masuko, Y Morioka, M Nakamura, Absorption structures of SF6 in the VUV region Journal of Physics B. ,vol. 11, pp. 3655- 3665 ,(1978) , 10.1088/0022-3700/11/21/011
W. Von Niessen, L.S. Cederbaum, G.H.F. Diercksen, G. Hohlneicher, The electronic structure of molecules by a many-body approach: VI. The assignment of the HeII photoelectron spectrum of SF6 Chemical Physics. ,vol. 11, pp. 399- 407 ,(1975) , 10.1016/0301-0104(75)80058-9
Ilya Prigogine, Stuart Alan Rice, Correlation Effects in the Ionization of Molecules: Breakdown of the Molecular Orbital Picture Advances in Chemical Physics. ,vol. 65, pp. 115- 159 ,(2007) , 10.1002/9780470142899.CH3
Farrel W. Lytle, Robert B. Greegor, Armand J. Panson, Discussion of x-ray-absorption near-edge structure: Application to Cu in the high-Tc superconductors La1.8Sr Physical Review B. ,vol. 37, pp. 1550- 1562 ,(1988) , 10.1103/PHYSREVB.37.1550
Robert E. LaVilla, Richard D. Deslattes, K‐Absorption Fine Structures of Sulfur in Gaseous SF6 The Journal of Chemical Physics. ,vol. 44, pp. 4399- 4400 ,(1966) , 10.1063/1.1726649
Karlheinz Schwarz, Optimization of the Statistical Exchange Parameter α for the Free Atoms H through Nb Physical Review B. ,vol. 5, pp. 2466- 2468 ,(1972) , 10.1103/PHYSREVB.5.2466
Thomas A. Carlson, Anders Fahlman, W. Agneta Svensson, M. O. Krause, Timothy A. Whitley, Frederick A. Grimm, M. N. Piancastelli, James W. Taylor, Angle‐resolved photoelectron cross section of CF4 Journal of Chemical Physics. ,vol. 81, pp. 3828- 3834 ,(1984) , 10.1063/1.448165
B.M. Addison, K.H. Tan, G.M. Bancroft, F. Cerrina, A comparison of shape resonant behaviour in the inner-shell photoabsorption and valence-level photoelectron spectra of SF6, SF5Cl and SeF6 Chemical Physics Letters. ,vol. 129, pp. 468- 474 ,(1986) , 10.1016/0009-2614(86)80230-5
M. G. Benedict, I. Gyemant, Total cross section of the SF6 molecule for elastic electron scattering International Journal of Quantum Chemistry. ,vol. 13, pp. 597- 603 ,(1978) , 10.1002/QUA.560130504
John S. Tse, Resonant enhancement in the valence orbital photoionization cross sections of xenon difluoride Journal of Chemical Physics. ,vol. 89, pp. 920- 928 ,(1988) , 10.1063/1.455215