The impact of trough geometry on film shape. A theoretical study of droplets containing polymer, for P-OLED display applications.

作者: Adam D. Eales , Nick Dartnell , Simon Goddard , Alexander F. Routh

DOI: 10.1016/J.JCIS.2015.07.036

关键词:

摘要: For P-OLED display fabrication, it is important to control the final film shape, arising from drying of volatile droplets containing polymer. Due peripheral pinning and subsequent outward capillary flow, a coffee-ring typically develops. This inconvenient since spatially uniform height, above substrate, required ensure current across device. Typically are deposited inside trough-like structure on substrate. We present thin-film lubrication model that tracks dynamics through shape. The governing equations derived solved numerically. investigate effect trough’s depth slope walls. Increasing or wall’s gradient increases formation. due an increase in horizontal velocity, caused by substrate’s shape as well delayed gelation latter allows flow act for longer time, before height becomes fixed.

参考文章(39)
Alexander W. Wray, Demetrios T. Papageorgiou, Richard V. Craster, Khellil Sefiane, Omar K. Matar, Electrostatic Suppression of the “Coffee-stain Effect” Procedia IUTAM. ,vol. 15, pp. 172- 177 ,(2015) , 10.1016/J.PIUTAM.2015.04.024
Robert D. Deegan, Olgica Bakajin, Todd F. Dupont, Greb Huber, Sidney R. Nagel, Thomas A. Witten, Capillary flow as the cause of ring stains from dried liquid drops Nature. ,vol. 389, pp. 827- 829 ,(1997) , 10.1038/39827
H. B. Eral, D. Mampallil Augustine, M. H. G. Duits, F. Mugele, Suppressing the coffee stain effect: how to control colloidal self-assembly in evaporating drops using electrowetting Soft Matter. ,vol. 7, pp. 4954- 4958 ,(2011) , 10.1039/C1SM05183K
Irvin M. Krieger, Thomas J. Dougherty, A Mechanism for Non‐Newtonian Flow in Suspensions of Rigid Spheres Journal of Rheology. ,vol. 3, pp. 137- 152 ,(1959) , 10.1122/1.548848
Adam D. Eales, Alexander F. Routh, Nick Dartnell, Goddard Simon, Evaporation of pinned droplets containing polymer – an examination of the important groups controlling final shape Aiche Journal. ,vol. 61, pp. 1759- 1767 ,(2015) , 10.1002/AIC.14777
Yu.Yu. Tarasevich, I.V. Vodolazskaya, O.P. Bondarenko, Modeling of spatial–temporal distribution of the components in the drying sessile droplet of biological fluid Colloids and Surfaces A: Physicochemical and Engineering Aspects. ,vol. 432, pp. 99- 103 ,(2013) , 10.1016/J.COLSURFA.2013.04.069
Robert D. Deegan, Olgica Bakajin, Todd F. Dupont, Greg Huber, Sidney R. Nagel, Thomas A. Witten, Contact line deposits in an evaporating drop Physical Review E. ,vol. 62, pp. 756- 765 ,(2000) , 10.1103/PHYSREVE.62.756
Torsten Goldmann, Juan S. Gonzalez, DNA-printing: utilization of a standard inkjet printer for the transfer of nucleic acids to solid supports Journal of Biochemical and Biophysical Methods. ,vol. 42, pp. 105- 110 ,(2000) , 10.1016/S0165-022X(99)00049-4
David Brutin, Benjamin Sobac, Céline Nicloux, Influence of Substrate Nature on the Evaporation of a Sessile Drop of Blood Journal of Heat Transfer-transactions of The Asme. ,vol. 134, pp. 061101- ,(2012) , 10.1115/1.4006033