Cooperative vibronic spectra involving rare earth ions and water molecules in hydrated salts and dilute aqueous solutions

作者: Michael Stavola , Louis Isganitis , Mark G. Sceats

DOI: 10.1063/1.441664

关键词:

摘要: Several cooperative vibronic bands have been observed in the excitation and emission spectra of polycrystalline hydrates dilute aqueous solutions TbCl3. A radiative transition involving simultaneous electronic a Tb3+ ion vibrational nearby water molecule gives rise to these bands. Theoretical calculations, based on an electrostatic coupling model, explain intensities transitions. Selection rules are derived quantitative estimates made.

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