Half-wave organic-rectifiers with donor/acceptor assemblies in the molecular scale
作者： Kallol Mohanta , Amlan J. Pal
DOI: 10.1016/J.ORGEL.2009.05.002
关键词:
摘要: We fabricate molecular rectifiers based on a monolayer of donor molecule and an acceptor in sequence. characterize the donor/acceptor assemblies under ac voltage. show that high-frequency half-wave can be fabricated characterized from assembly. From frequency-response rectifiers, we study time responses processes are responsible for observed rectification. comment three steps rectifier - being electron-transfer to moiety, electron-withdrawal charge-transfer between anionic-acceptor cationic-donor. The results latter process is slow one may due conformational-change anionic-acceptors upon oxidation.
elsevier.com
sci-hub.se 参考文章(14)
Soeren Steudel, Kris Myny, Vladimir Arkhipov, Carsten Deibel, Stijn De Vusser, Jan Genoe, Paul Heremans, 50 MHz rectifier based on an organic diode Nature Materials. ,vol. 4, pp. 597- 600 ,(2005) , 10.1038/NMAT1434
Kazuya Kitagawa, Tomoyuki Morita, Shunsaku Kimura, Molecular rectification of a helical peptide with a redox group in the metal-molecule-metal junction. Journal of Physical Chemistry B. ,vol. 109, pp. 13906- 13911 ,(2005) , 10.1021/JP050642E
Geoffrey J. Ashwell, Wayne D. Tyrrell, Anne J. Whittam, Molecular rectification: Self-assembled monolayers in which donor-(π-bridge)-acceptor moieties are centrally located and symmetrically coupled to both gold electrodes Journal of the American Chemical Society. ,vol. 126, pp. 7102- 7110 ,(2004) , 10.1021/JA049633U
Kris Myny, Soeren Steudel, Peter Vicca, Jan Genoe, Paul Heremans, An integrated double half-wave organic Schottky diode rectifier on foil operating at 13.56 MHz Applied Physics Letters. ,vol. 93, pp. 093305- ,(2008) , 10.1063/1.2978348
Steven K. Pollack, Jawad Naciri, John Mastrangelo, Charles H. Patterson, Johnny Torres, Martin Moore, Ranganathan Shashidhar, James G. Kushmerick, Sequential deprotection for control of orientation in the self-assembly of asymmetric molecules for molecular electronic devices Langmuir. ,vol. 20, pp. 1838- 1842 ,(2004) , 10.1021/LA036170H
Archana Jaiswal, Ramiya R. Amaresh, M. V. Lakshmikantham, Andrei Honciuc, Michael P. Cava, Robert M. Metzger, Electrical rectification in a monolayer of zwitterions assembled by either physisorption or chemisorption Langmuir. ,vol. 19, pp. 9043- 9050 ,(2003) , 10.1021/LA034073I
J SUN, B PAL, B JUNG, H KATZ, Solution-processed hybrid p-n junction vertical diode Organic Electronics. ,vol. 10, pp. 1- 7 ,(2009) , 10.1016/J.ORGEL.2008.08.016
Robert M. Metzger, Bo Chen, Ulf Höpfner, M. V. Lakshmikantham, Dominique Vuillaume, Tsuyoshi Kawai, Xiangli Wu, Hiroaki Tachibana, Terry V. Hughes, Hiromi Sakurai, Jeffrey W. Baldwin, Christina Hosch, Michael P. Cava, Ludwig Brehmer, Geoffrey J. Ashwell, UNIMOLECULAR ELECTRICAL RECTIFICATION IN HEXADECYLQUINOLINIUM TRICYANOQUINODIMETHANIDE Journal of the American Chemical Society. ,vol. 119, pp. 10455- 10466 ,(1997) , 10.1021/JA971811E
Michael L. Chabinyc, Xiaoxi Chen, R. Erik Holmlin, Heiko Jacobs, Hjalti Skulason, C. Daniel Frisbie, Vladimiro Mujica, Mark A. Ratner, Maria Anita Rampi, George M. Whitesides, Molecular rectification in a metal-insulator-metal junction based on self-assembled monolayers Journal of the American Chemical Society. ,vol. 124, pp. 11730- 11736 ,(2002) , 10.1021/JA020506C
Biswanath Mukherjee, Kallol Mohanta, Amlan J. Pal, Tuning of molecular rectification in donor/acceptor assemblies via supramolecular structures Chemistry of Materials. ,vol. 18, pp. 3302- 3307 ,(2006) , 10.1021/CM060757A