Concentration quenching of Tb3+ luminescence in LaOBr and Gd2O2S phosphors

作者: Jorma Hölsä , Markku Leskelä , Lauri Niinistö

DOI: 10.1016/0025-5408(79)90082-5

关键词:

摘要: Abstract The concentration quenching of trivalent terbium 5 D 3,4 → 7 F J emissions from UV-excited (La, Tb) OBr and (Gd, 2 O S phosphors was studied. activation x varied 5·10 −5 to 0.2 for (La 1−x Tb ) 10 −3 0.1 (Gd S. 3 (blue) were observed quench first the 3+ giving rise maximum intensity 0.003 in between 0.005 0.01 optimum 4 (green) 0.05 0.03 Dipole-dipole dipole-quadrupole interactions are possible mechanisms levels. A method determining these phosphors, based on ratios transitions, is also presented.

参考文章(12)
S. S. Sidhu, Deuterium Effect on Hydrogen Bond Distances in Hafnium Dihydride The Journal of Chemical Physics. ,vol. 22, pp. 1062- 1063 ,(1954) , 10.1063/1.1740264
Lyuji Ozawa, Herbert N. Hersh, Concentration Dependence Curves of Y 2 O 2 S : Eu Journal of The Electrochemical Society. ,vol. 122, pp. 1222- 1225 ,(1975) , 10.1149/1.2134429
Markus Koskenlinna, Markku Leskelä, Lauri Niinistö, Synthesis and Luminescence Properties of Europium‐Activated Yttrium Oxysulfide Phosphors Journal of The Electrochemical Society. ,vol. 123, pp. 75- 78 ,(1976) , 10.1149/1.2132770
N. P. Efryushina, E. A. Zhikhareva, Concentrational quenching of UV- and x-ray-excited luminescence of lanthanide ions in crystal phosphors Journal of Applied Spectroscopy. ,vol. 26, pp. 347- 350 ,(1977) , 10.1007/BF00617441
L. Ozawa, H. Forest, P. M. Jaffe, G. Ban, The Effect of Exciting Wavelength on Optimum Activator Concentration Journal of The Electrochemical Society. ,vol. 118, pp. 482- 486 ,(1971) , 10.1149/1.2408087
D. L. Dexter, A Theory of Sensitized Luminescence in Solids The Journal of Chemical Physics. ,vol. 21, pp. 836- 850 ,(1953) , 10.1063/1.1699044
G. Blasse, Some considerations on rare-earth activated phosphors Journal of Luminescence. ,vol. 1-2, pp. 766- 777 ,(1970) , 10.1016/0022-2313(70)90089-X
Lyuji. Ozawa, Harvey. Forest, Determination of trivalent europium concentration in yttrium oxysulfide phosphor Analytical Chemistry. ,vol. 45, pp. 978- 979 ,(1973) , 10.1021/AC60328A023
Lyuji Ozawa, Philip M. Jaffe, The Mechanism of the Emission Color Shift with Activator Concentration in +3 Activated Phosphors Journal of The Electrochemical Society. ,vol. 118, pp. 1678- 1679 ,(1971) , 10.1149/1.2407810
L. G. Van Uitert, Characterization of Energy Transfer Interactions between Rare Earth Ions Journal of The Electrochemical Society. ,vol. 114, pp. 1048- 1053 ,(1967) , 10.1149/1.2424184