Analytical investigations of the problem of “Kupferfra\” in illuminated manuscripts

作者: Gerhard Banik , H. Stachelberger , F. Mairinger , A. Vendl , J. Ponahlo

DOI: 10.1007/BF01198703

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摘要: The paper gives an introductory survey of the complex problem “Kupferfras”. Possible chemical changes in copper pigments, caused by environmental influences or reduction with other components paint layer cellulose are discussed. Attempts to characterize some pigments have been successful. Reactions different green can be detected infrared spectroscopy. In all decayed samples, Cl and S energy-dispersive presence basic chlorides seems proved although structural identification has not so far possible. above-mentioned results make assumption that browning carrier is a Fehling-type reaction. initial step yet quite clear, however.

参考文章(3)
R. I. C. MICHIE, Sorption of Copper by Cellulose Nature. ,vol. 190, pp. 803- 804 ,(1961) , 10.1038/190803A0
W. A. BELL, Catalytic Effects in the Alkaline Oxidation of Cellulose Nature. ,vol. 186, pp. 963- 964 ,(1960) , 10.1038/186963B0
R. I. C. Michie, S. M. Neale, 11—THE EFFECT OF COPPER AND IRON ON THE PHOTODEGRADATION OF COTTON Journal of The Textile Institute Transactions. ,vol. 55, ,(1964) , 10.1080/19447026408660219