Ligand Displacement from TpMn(CO)2L Complexes: A Large Rate Enhancement in Comparison to the CpMn(CO)2L Analogues
作者： Bert H. G. Swennenhuis , Ross Poland , Nathan J. DeYonker , Charles Edwin Webster , Donald J. Darensbourg
DOI: 10.1021/OM200161G
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摘要: The mechanism and energetics of ligand (L) displacement from TpMn(CO)2L (L = cyclooctene, HSiEt3) complexes was studied using time-resolved infrared spectroscopy DFT. While the dissociative sub...
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