Carbene Complexes Derived from the Activation of Isocyanides and Alkynes by Electron-Rich Metal Centres
DOI: 10.1007/978-94-009-2317-1_10
关键词:
摘要: Isocyanides (C≡NR) and alkynes react with electron-rich d6 Mo-, W- or Re-phosphinic centres (M) to give complexes short metal-carbon bond distances, where the derived organic ligand may present at least a partial carbene character. In these reactions undergo metal-centred rearrangements involving hydrogen-migration vinylidene (M=C=CHR), allene Open image in new window alkynyl (M-C≡CR)
springer.com
sci-hub.st 参考文章(81)
J.R. Dilworth, R.L. Richards, Reactions of Dinitrogen Promoted by Transition Metal Compounds Comprehensive Organometallic Chemistry. ,vol. 60, pp. 1073- 1106 ,(1982) , 10.1016/B978-008046518-0.00124-0
Piero Pino, Irving Wender, Organic syntheses via metal carbonyls Interscience Publishers. ,(1968)
Peter Wiseman, T. P. Wiseman, An introduction to industrial organic chemistry ,(1972)
Paul M. Treichel, Transition Metal-lsocyanide Complexes Advances in Organometallic Chemistry. ,vol. 11, pp. 21- 86 ,(1973) , 10.1016/S0065-3055(08)60159-8
Sei Otsuka, Akira Nakamura, Acetylene and Allene Complexes: Their Implication in Homogeneous Catalysis Advances in Organometallic Chemistry. ,vol. 14, pp. 245- 283 ,(1976) , 10.1016/S0065-3055(08)60654-1
Heesook P. Kim, Robert J. Angelici, Transition metal complexes with terminal carbyne ligands Advances in Organometallic Chemistry. ,vol. 27, pp. 51- 111 ,(1987) , 10.1016/S0065-3055(08)60026-X
Eric Singleton, Hester E. Oosthuizen, Metal Isocyanide Complexes Advances in Organometallic Chemistry. ,vol. 22, pp. 209- 310 ,(1983) , 10.1016/S0065-3055(08)60404-9
C A Heaton, An Introduction to Industrial Chemistry ,(1991)
Ernst otto Fischer, Ulrich Schubert, Übergangsmetall—carbin-komplexe : VII. Darstellung, eigenschaften und reaktionsverhalten von übergangsmetallcarbonyl—carbin-komplexen☆ Journal of Organometallic Chemistry. ,vol. 100, pp. 59- 81 ,(1975) , 10.1016/S0022-328X(00)88934-2
Richard A. Henderson, G Jeffery Leigh, Christopher J. Pickett, The Chemistry of Nitrogen Fixation and Models for The Reactions of Nitrogenase Advances in Inorganic Chemistry. ,vol. 27, pp. 197- 292 ,(1983) , 10.1016/S0898-8838(08)60108-7