A terahertz absorption spectroscopy study of structural changes in D-penicillaminato CuI8CuII6 clusters induced by water desorption
作者： Hal Suzuki , Chiko Otani , Nobuto Yoshinari , Takumi Konno
DOI: 10.1039/C5QI00207A
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摘要: Structural changes induced by water desorption from D-penicillaminato (D-pen) CuI8CuII6 clusters aggregated into three polymorphic crystal structures ((1) 1D helical, (2) 2D hexagonal sheet, and (3) discrete cubic) were investigated terahertz (THz) absorption spectroscopy X-ray diffractometry (XRD), which provided information on the skeletal of clusters, respectively. The molecules incorporated crystals removed evacuation heating to 100 °C. In case 1, helical structure collapsed upon evacuation, whereas D-pen did not change. However, distorted process. For 2 3, affect either or sheet cubic which, however, heating. mechanisms driving these structural discussed in relation type amount each
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