Chemoselective, iron(II)-catalyzed oxidation of a variety of secondary alcohols over primary alcohols utilizing H2O2 as the oxidant

作者: Matthew Lenze , Eike B. Bauer

DOI: 10.1039/C3CC41131A

关键词:

摘要: A mild, iron-based catalyst system is presented that selectively oxidizes secondary alcohols to the corresponding hydroxy ketones in presence of primary within 15 minutes at room temperature, utilizing H2O2 as oxidant.

参考文章(41)
Krzysztof Barbusiński, Fenton reaction - controversy concerning the chemistry Ecological Chemistry and Engineering S-chemia I Inzynieria Ekologiczna S. ,vol. 16, pp. 347- 358 ,(2009)
Andrei V. Bekish, Carbon–carbon bond fission on oxidation of primary alcohols to carboxylic acids Tetrahedron Letters. ,vol. 53, pp. 3082- 3085 ,(2012) , 10.1016/J.TETLET.2012.04.035
Benjamin D. Sherry, Alois Fürstner, The Promise and Challenge of Iron-Catalyzed Cross Coupling Accounts of Chemical Research. ,vol. 41, pp. 1500- 1511 ,(2008) , 10.1021/AR800039X
Eike Bauer, Recent Advances in Iron Catalysis in Organic Synthesis Current Organic Chemistry. ,vol. 12, pp. 1341- 1369 ,(2008) , 10.2174/138527208786241556
Éva Balogh-Hergovich, Gábor Speier, Catalytic oxidation of alcohols to carbonyl compounds with hydrogen peroxide using dinuclear iron complexes Journal of Molecular Catalysis A: Chemical. ,vol. 230, pp. 79- 83 ,(2005) , 10.1016/J.MOLCATA.2004.12.013
Benoît Join, Konstanze Möller, Carolin Ziebart, Kristin Schröder, Dirk Gördes, Kerstin Thurow, Anke Spannenberg, Kathrin Junge, Matthias Beller, Selective Iron-Catalyzed Oxidation of Benzylic and Allylic Alcohols Advanced Synthesis & Catalysis. ,vol. 353, pp. 3023- 3030 ,(2011) , 10.1002/ADSC.201100210
Hassan Hosseini-Monfared, Christian Näther, Heiner Winkler, Christoph Janiak, Highly selective and “green” alcohol oxidations in water using aqueous 10% H2O2 and iron-benzenetricarboxylate metal–organic gel Inorganica Chimica Acta. ,vol. 391, pp. 75- 82 ,(2012) , 10.1016/J.ICA.2012.05.007
Ah-Rim Han, Yu Jin Jeong, Yaeun Kang, Jung Yoon Lee, Mi Sook Seo, Wonwoo Nam, Direct evidence for an iron(IV)-oxo porphyrin π-cation radical as an active oxidant in catalytic oxygenation reactions Chemical Communications. pp. 1076- 1078 ,(2008) , 10.1039/B716558G