Anodic decomposition of alpha-CuI on glassy carbon

作者: J.A. Schmidt , M.R. Prat

DOI: 10.1016/0254-0584(96)01744-0

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摘要: Abstract The kinetics of the anodic reaction at CuI/glassy carbon interface was studied. Tafel-type behavior found, with two alternative processes: charge transport by electronic holes, predominant low overpotentials, in parallel always present decomposition electrolyte interface, rate-controlling step latter process being recombination adsorbed iodine atoms.

参考文章(15)
R. Tunold, A. Vatland, The kinetics of the bromine electrode in a silver bromide-sodium bromide melt Electrochimica Acta. ,vol. 19, pp. 375- 382 ,(1974) , 10.1016/0013-4686(74)87011-8
B. E. Conway, Robert Greef, Theory and Principles of Electrode Processes ,(1965)
W.E. Triaca, C. Solomons, J.O'M. Bockris, The mechanism of the electrolytic evolution and dissolution of chlorine on graphite Electrochimica Acta. ,vol. 13, pp. 1949- 1964 ,(1968) , 10.1016/0013-4686(68)80105-7
Bernhard Ilschner, Determination of the Electronic Conductivity in Silver Halides by Means of Polarization Measurements Journal of Chemical Physics. ,vol. 28, pp. 1109- 1112 ,(1958) , 10.1063/1.1744352
J. C. Baz�n, J. A. Schmidt, A Cu(I) ion conductor obtained by replacement of Ag(I) in ?-AgI Journal of Applied Electrochemistry. ,vol. 6, pp. 411- 415 ,(1976) , 10.1007/BF00616540
Walter J. Hamer, Marjorie S. Malmberg, Bernard Rubin, Theoretical Electromotive Forces for Cells Containing a Single Solid or Molten Fluoride, Bromide, or Iodide Journal of The Electrochemical Society. ,vol. 112, pp. 750- 755 ,(1965) , 10.1149/1.2423683
J.C. Bazán, M.R. Prat, J.A. Schmidt, On the kinetics of Cu(I) transfer through the solid CuI-Cu interface Materials Chemistry and Physics. ,vol. 24, pp. 473- 485 ,(1990) , 10.1016/0254-0584(90)90135-W
J. Bruce Wagner, Carl Wagner, Electrical Conductivity Measurements on Cuprous Halides The Journal of Chemical Physics. ,vol. 26, pp. 1597- 1601 ,(1957) , 10.1063/1.1743590
Juan M. Aceves, Anthony R. West, Electrochemical decomposition of Li4SiO4 and Li2TiO3 in solid-state thermal cells Journal of the Chemical Society, Faraday Transactions. ,vol. 78, pp. 2599- 2608 ,(1982) , 10.1039/F19827802599