Dipolar Interaction in a Bipolar System-Long-Chain Aliphatic Alcohols with Carboxylic Acids

作者: Kalpana Garabadu , Bipin Behari Swain

DOI: 10.1080/00319109608029558

关键词:

摘要: Abstract Dielectric constant of binary mixtures some long-chain aliphatic alcohols i.e. n-propanol, n-pentanol, n-hexanol, n-heptanol and n-octanol with propionic acid butyric measured at 455 kHz 303.16 K are utilised to calculate mutual correlation factor gab , excess molar polarization Δp free energy mixing ΔFab in those mixtures. The results indicate that acid-alcohol interaction is stronger system than the system.

参考文章(5)
F. X. HASSION, R. H. COLE, Dielectric Relaxation Processes in Ethanol Nature. ,vol. 172, pp. 212- 213 ,(1953) , 10.1038/172212A0
F. X. Hassion, R. H. Cole, Dielectric Properties of Liquid Ethanol and 2‐Propanol The Journal of Chemical Physics. ,vol. 23, pp. 1756- 1761 ,(1955) , 10.1063/1.1740575
B. B. Swain, K. Garabadu, Dielectric response of some long-chain alcohols in non polar solvents Indian Journal of Pure & Applied Physics. ,vol. 31, pp. 741- 743 ,(1993)
V. Rajendran, A. N. Kannappan, Effect of free volume and internal pressure on ion-solvent interaction of some aqueous electrolytic solutions Indian Journal of Pure & Applied Physics. ,vol. 31, pp. 354- 357 ,(1993)