Transition metal complexes with pyrazole-based ligands. Part 6.: Synthesis, characterization and thermal decomposition of cadmium complexes with 3(5)-amino-5(3)-methylpyrazole
作者： K. Mészáros Szécsényi , E.Z. Ivegeš , V.M. Leovac , Lj.S. Vojinović , A. Kovács
DOI: 10.1016/S0040-6031(98)00292-5
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摘要: Abstract The synthesis, IR-spectra and thermal analysis of tetrahedral or octahedral Cd(II)-complexes 3(5)-amino-5(3)-methylpyrazole (L), as represented by the general formula CdX 2 L · n H O ( X = NCS − , NCO Cl =2; 1/2 SO 2− 4 =1), complex Cd(OAc) 3 ·H are described. Thermal decomposition acetato results in an intermediate, appearing 480–580 K range. On basis IR-spectrum elemental a scheme is proposed. Because involvement different anion, other complexes differs from that complex.
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