Stability and Conformation of Silicon-Carbon Compounds. A Case Study of SiC2, Si2C and Si3
作者： Jens Oddershede , John R. Sabine , Geerd H. F. Diercksen
DOI: 10.1007/978-94-009-3781-9_29
关键词:
摘要: We discuss the binding in C2, SiC, Si2, C3, SiC2, Si2C and Si3 molecules terms of an orbital picture. Walsh diagrams are used to give understanding geometry triatomic their ground excited states. show that introduction silicon atoms homologous series tends decrease strength bonds make compounds more stable bent conformation.
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James A. Ibers, Lonsdale, Kathleen, Dame, John S. Kasper, Gerard D. Rieck, Walter C. Hamilton, Norman Fordyce McKerron Henry, Caroline H. MacGillavry, International tables for X-ray crystallography UT Back-in-Print Service. ,(1962)
Jens Oddershede, Polarization Propagator Calculations Advances in Quantum Chemistry. ,vol. 11, pp. 275- 352 ,(1978) , 10.1016/S0065-3276(08)60240-3
Carl Johan Ballhausen, Molecular electronic structures of transition metal complexes ,(1979)
M. R. Chedekel, M. Skoglund, R. L. Kreeger, H. Shechter, Solid state chemistry. Discrete trimethysilylmethylene Journal of the American Chemical Society. ,vol. 98, pp. 7846- 7848 ,(1976) , 10.1021/JA00440A077
J. Drowart, G. De Maria, Mark G. Inghram, Thermodynamic Study of SiC Utilizing a Mass Spectrometer The Journal of Chemical Physics. ,vol. 29, pp. 1015- 1021 ,(1958) , 10.1063/1.1744646
Shu Murakami, Scott Collins, Satoru Masamune, Photo-induced fragmentation of tri-t-butyl-trimesityl- cyclotrisilanes and E,Z-interconversion of di-t-butyl-dimesityl-disilenes Tetrahedron Letters. ,vol. 25, pp. 2131- 2134 ,(1984) , 10.1016/S0040-4039(01)81180-1
Mark J. Fink, Michael J. Michalczyk, Kenneth J. Haller, Josef Michl, Robert West, X-ray crystal structures for two disilenes Organometallics. ,vol. 3, pp. 793- 800 ,(1984) , 10.1021/OM00083A025
R. O. Jones, Energy surfaces of low‐lying states of C3 Journal of Chemical Physics. ,vol. 82, pp. 5078- 5083 ,(1985) , 10.1063/1.448629
R. W. Kilb, Louis Pierce, Microwave Spectrum, Structure, and Internal Barrier of Methyl Silane The Journal of Chemical Physics. ,vol. 27, pp. 108- 112 ,(1957) , 10.1063/1.1743646
Dean H. Liskow, Charles F. Bender, Henry F. Schaefer, Bending Frequency of the C3 Molecule The Journal of Chemical Physics. ,vol. 56, pp. 5075- 5080 ,(1972) , 10.1063/1.1676990