Structural characterization of the Fddd phase in a diblock copolymer thin film by electron microtomography
作者： Jueun Jung , Hae-Woong Park , Junyoung Lee , Haiying Huang , Taihyun Chang
DOI: 10.1039/C1SM06236K
关键词:
摘要: A 3-dimensional Fddd network structure of a polystyrene-block-polyisoprene (PS-b-PI) diblock copolymer (Mn = 31500, fPI 0.645) was observed for the first time in real space by transmission electron microtomography (TEMT). In 650 nm thick film PS-b-PI thin on silicon wafer, phase developed after annealing at 215 °C 24 h. The single consists connected tripodal units minor PS block domains. {111}Fddd plane, densest plane phase, found to orient parallel plane. transitional from wetting layer free surface internal via perforated also observed.
rsc.org
harvard.edu
elsevier.com
postech.ac.kr参考文章(50)
Shotaro Nishitsuji, Tsutomu Wakada, Satoshi Akasaka, Mikihito Takenaka, Kenji Saijo, Hirofumi Shimizu, Hirokazu Hasegawa, Myung Im Kim, Orthorhombic Fddd Network in Diblock Copolymer Melts Macromolecules. ,vol. 40, pp. 4399- 4402 ,(2007) , 10.1021/MA070739U
M. W. Matsen, Thin films of block copolymer Journal of Chemical Physics. ,vol. 106, pp. 7781- 7791 ,(1997) , 10.1063/1.473778
Han-Yu Hsueh, Hung-Ying Chen, Ming-Shiuan She, Chun-Ku Chen, Rong-Ming Ho, Shangjr Gwo, Hirokazu Hasegawa, Edwin L. Thomas, Inorganic Gyroid with Exceptionally Low Refractive Index from Block Copolymer Templating Nano Letters. ,vol. 10, pp. 4994- 5000 ,(2010) , 10.1021/NL103104W
Hiroshi Jinnai, Richard J. Spontak, Toshio Nishi, Transmission Electron Microtomography and Polymer Nanostructures Macromolecules. ,vol. 43, pp. 1675- 1688 ,(2010) , 10.1021/MA902035P
Changhak Shin, Hyungju Ahn, Eunhye Kim, Du Yeol Ryu, June Huh, Kwang-Woo Kim, Thomas P. Russell, Transition behavior of block copolymer thin films on preferential surfaces Macromolecules. ,vol. 41, pp. 9140- 9145 ,(2008) , 10.1021/MA801778M
Insun Park, Byeongdu Lee, Jinsook Ryu, Kyuhyun Im, Jinhwan Yoon, Moonhor Ree, Taihyun Chang, Epitaxial Phase Transition of Polystyrene-b-Polyisoprene from Hexagonally Perforated Layer to Gyroid Phase in Thin Film Macromolecules. ,vol. 38, pp. 10532- 10536 ,(2005) , 10.1021/MA051137I
M. W. Matsen, Fast and accurate SCFT calculations for periodic block-copolymer morphologies using the spectral method with Anderson mixing European Physical Journal E. ,vol. 30, pp. 361- 369 ,(2009) , 10.1140/EPJE/I2009-10534-3
Myung Im Kim, Tsutomu Wakada, Satoshi Akasaka, Shotaro Nishitsuji, Kenji Saijo, Hirokazu Hasegawa, Kazuki Ito, Mikihito Takenaka, Determination of the Fddd Phase Boundary in Polystyrene-block-polyisoprene Diblock Copolymer Melts Macromolecules. ,vol. 42, pp. 5266- 5271 ,(2009) , 10.1021/MA900205S
Eric W. Cochran, Frank S. Bates, Shear-induced network-to-network transition in a block copolymer melt Physical Review Letters. ,vol. 93, pp. 087802- ,(2004) , 10.1103/PHYSREVLETT.93.087802
Hidekazu Sugimori, Toshio Nishi, Hiroshi Jinnai, Dual-Axis Electron Tomography for Three-Dimensional Observations of Polymeric Nanostructures Macromolecules. ,vol. 38, pp. 10226- 10233 ,(2005) , 10.1021/MA051705U