Effect of fabrication parameters on the electrical conductivity of YxSr1−xTiO3 for anode materials
作者： Xianliang Huang , Hailei Zhao , Wei Shen , Weihua Qiu , Weijiang Wu
DOI: 10.1016/J.JPCS.2006.08.004
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摘要: Abstract Yttrium-doped strontium titanate (YxSr1−xTiO3), as probable anode material for SOFC, was prepared by solid-state reaction. The solubility of yttrium in SrTiO3 at different temperatures examined and the electrical conductivities YxSr1−xTiO3 were measured from 500 to 1000 °C. effects doping amount, fabrication atmosphere, sintering temperature on conductivity investigated. with x = 0.08 found give maximum conductivity, 71 S/cm 800 °C pure hydrogen. Reducing atmospheres appropriate play a positive role improving conductivity.
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Andrew Murray, Cell cycle: A snip separates sisters Nature. ,vol. 400, pp. 19- 21 ,(1999) , 10.1038/21781
H. P. R. Frederikse, W. R. Hosler, Hall Mobility in SrTiO 3 Physical Review. ,vol. 161, pp. 822- 827 ,(1967) , 10.1103/PHYSREV.161.822
E. Perry Murray, T. Tsai, S. A. Barnett, A direct-methane fuel cell with a ceria-based anode Nature. ,vol. 400, pp. 649- 651 ,(1999) , 10.1038/23220
J.P.P Huijsmans, F.P.F van Berkel, G.M Christie, Intermediate temperature SOFC – a promise for the 21st century Journal of Power Sources. ,vol. 71, pp. 107- 110 ,(1998) , 10.1016/S0378-7753(97)02789-4
F.H Wang, R.S Guo, Q.T Wei, Y Zhou, H.L Li, S.L Li, Preparation and properties of Ni/YSZ anode by coating precipitation method Materials Letters. ,vol. 58, pp. 3079- 3083 ,(2004) , 10.1016/J.MATLET.2004.05.047
Yoshio Matsuzaki, Isamu Yasuda, The poisoning effect of sulfur-containing impurity gas on a SOFC anode: Part I. Dependence on temperature, time, and impurity concentration Solid State Ionics. ,vol. 132, pp. 261- 269 ,(2000) , 10.1016/S0167-2738(00)00653-6
Ralf Moos, Karl Heinz Hardtl, Defect Chemistry of Donor‐Doped and Undoped Strontium Titanate Ceramics between 1000° and 1400°C Journal of the American Ceramic Society. ,vol. 80, pp. 2549- 2562 ,(2005) , 10.1111/J.1151-2916.1997.TB03157.X
Mogens Mogensen, Karin Vels Jensen, Mette Juhl Jørgensen, Søren Primdahl, Progress in understanding SOFC electrodes Solid State Ionics. ,vol. 150, pp. 123- 129 ,(2002) , 10.1016/S0167-2738(02)00269-2
Shiqiang Hui, Anthony Petric, Evaluation of yttrium-doped SrTiO3 as an anode for solid oxide fuel cells Journal of The European Ceramic Society. ,vol. 22, pp. 1673- 1681 ,(2002) , 10.1016/S0955-2219(01)00485-X
O. N. Tufte, P. W. Chapman, Electron Mobility in Semiconducting Strontium Titanate Physical Review. ,vol. 155, pp. 796- 802 ,(1967) , 10.1103/PHYSREV.155.796