Thermodynamics of liquid mixtures containing methyl methylthiomethyl sulfoxide. I: Excess volumes of (water or benzene or dimethyl sulfoxide + methyl methylthiomethyl sulfoxide) and (water or benzene + dimethyl sulfoxide) at 298.15 and 318.15 K

作者: Takayoshi Kimura , Sadao Takagi

DOI: 10.1016/0021-9614(86)90092-3

关键词:

摘要: Abstract To compare the difference between thermodynamic properties of binary mixtures containing methyl methylthiomethyl sulfoxide ( mmtso ), CH 3 (CH SCH 2 )SO, and those dimethyl dmso excess molar volumes for title have been determined by use bicapillary pyknometers. The signs their temperature coefficients are similar to corresponding . curve volume (water + ) plotted against mole fraction x shows an inflection point in range:

参考文章(10)
K. Ogura, G. Tsuchihashi, Nucleophilic substitution of α-chloro-sulphoxides J. Chem. Soc. D. ,vol. 0, pp. 1689- 1690 ,(1970) , 10.1039/C29700001689
P. G. Sears, W. H. Fortune, R. L. Blumenshine, Dipole Moment of Sulfamic Acid and Viscosities of Its Solutions in Selected Nonaqueous Media. Journal of Chemical & Engineering Data. ,vol. 11, pp. 406- 409 ,(1966) , 10.1021/JE60030A035
Katsuyuki Ogura, Gen-ichi Tsuchihashi, A Convenient Synthesis of Methyl Methylthiomethyl Sulfoxide Bulletin of the Chemical Society of Japan. ,vol. 45, pp. 2203- 2204 ,(1972) , 10.1246/BCSJ.45.2203
Takayoshi Kimura, Sadao Takagi, Determination of excess volumes of benzene +o-terphenyl at 288.15, 298.02, and 302.78 K The Journal of Chemical Thermodynamics. ,vol. 11, pp. 119- 124 ,(1979) , 10.1016/0021-9614(79)90160-5
G. S. Kell, Precise representation of volume properties of water at one atmosphere Journal of Chemical & Engineering Data. ,vol. 12, pp. 66- 69 ,(1967) , 10.1021/JE60032A018
J. M. G. Cowie, P. M. Toporowski, ASSOCIATION IN THE BINARY LIQUID SYSTEM DIMETHYL SULPHOXIDE – WATER Canadian Journal of Chemistry. ,vol. 39, pp. 2240- 2243 ,(1961) , 10.1139/V61-296
Scott E. Wood, James P. Brusie, The Volume of Mixing and the Thermodynamic Functions of Benzene—Carbon Tetrachloride Mixture1 Journal of the American Chemical Society. ,vol. 65, pp. 1891- 1895 ,(1943) , 10.1021/JA01250A028
CF Lau, PT Wilson, DV Fenby, Excess volumes of dimethyl sulphoxide mixtures Australian Journal of Chemistry. ,vol. 23, pp. 1143- 1148 ,(1970) , 10.1071/CH9701143
Tooru Atake, Yasutoshi Saito, Kazuya Saito, Theoretical Analysis of Classical DTA, Power-compensated DSC and Heat-flux DSC Netsu Sokutei. ,vol. 14, pp. 2- 11 ,(1987) , 10.11311/JSCTA1974.14.2
Sadao Takagi, Purity determination by thermal analysis Netsu Sokutei. ,vol. 9, pp. 124- 131 ,(1982) , 10.11311/JSCTA1974.9.124