Electrochemical oxidation of hydrosilanes. A synthetic approach to halosilanes and disilanes
作者： Atsutaka Kunai , Toshihiro Kawakami , Eiji Toyoda , Tomohiro Sakurai , Mitsuo Ishikawa
DOI: 10.1246/CL.1993.1945
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摘要: Electrolytic oxidation of dimethylphenylsilane (1) in the presence CuCl2 or CuCl afforded chlorodimethylphenylsilane high yields ( >90%), while similar electrolysis 1 BF4− ions fluorodimethylphenylsilane 90% yield. 1,2-Diphenyltetramethyldisilane was obtained from 48% yield by with a Pt–Cu electrode system. A “paired” methyldiphenylsilane on anode and chloromethyldiphenylsilane cathode 1,2-dimethyltetraphenyldisilane 64%
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