Radical Additions of Heptafluoropropyl Trifluorovinyl Ether
作者： Akihiro Hosoya , Tadashi Narita , Hiroshi Hamana
DOI: 10.1135/CCCC20081663
关键词:
摘要: The radical addition reactions of heptafluoropropyl trifluorovinyl ether (CF2=CF-O-C3F7) with cyclic ethers such as tetrahydrofuran, tetrahydropyran, 1,4-dioxane and 1,3-dioxolane were investigated to afford the corresponding one to one addition products in fairly high yields in the presence of dibenzoyl peroxide at 60 °C. The method provides a facile way to prepare cyclic ethers possessing fluoroalkyl substituents.
sci-hub.se 参考文章(8)
Oldřich Paleta, Vladimír Církva, Jaroslav Kvicala, Radical additions to fluoro-olefins. Photochemical mono-fluoroalkylation and sequential bis-fluoroalkylation of oxolane Journal of Fluorine Chemistry. ,vol. 80, pp. 125- 134 ,(1996) , 10.1016/S0022-1139(96)03511-7
Tadashi Narita, Novel fluorinated polymers by radical polyaddition: Inspiration and progress Journal of Polymer Science Part A. ,vol. 42, pp. 4101- 4125 ,(2004) , 10.1002/POLA.20273
Tadashi Narita, Kazuyuki Enomoto, Yasunari Maekawa, Masaru Yoshida, Mitsuru Ichikawa, Hiroshi Hamana, γ-Rays radiation-induced homopolymerization of trifluorovinyl heptafluoropropyl ether Journal of Fluorine Chemistry. ,vol. 128, pp. 52- 54 ,(2007) , 10.1016/J.JFLUCHEM.2006.08.009
Tadashi Narita, Tokio Hagiwara, Hiroshi Hamana, Kazuyuki Enomoto, Yasuhiko Yoshida, Yuuichi Inagaki, Radical polyaddition of bis(α-trifluoromethyl-β-difluorovinyl) terephthalate with 1,4-dioxane Macromolecular Rapid Communications. ,vol. 19, pp. 485- 491 ,(1998) , 10.1002/(SICI)1521-3927(19980901)19:9<485::AID-MARC485>3.0.CO;2-L
Vladimı́r Cı́rkva, Oldrich Paleta, Radical addition reactions of fluorinated species. Part 7. Highly selective two-step synthesis of 1-(polyfluoroalkyl)ethane-1,2-diols; regioselectivity of the additions of methylated 1,3-dioxolanes to perfluoroolefins Journal of Fluorine Chemistry. ,vol. 94, pp. 141- 156 ,(1999) , 10.1016/S0022-1139(98)00356-X
Tadashi Narita, Yoshiomi Sakuragi, Hiroaki Yabata, Daisuke Kimura, Hiroshi Hamana, Synthesis and polymerization of novel fluorinated acrylates and methacrylates bearing alkoxyl groups derived from radical addition reaction of perfluoroisopropenyl ester Journal of Fluorine Chemistry. ,vol. 128, pp. 965- 970 ,(2007) , 10.1016/J.JFLUCHEM.2007.04.025
I Smart, MC, Ratnakumar, BV, Ryan-Mowrey, VS, Surampudi, , Prakash, GKS, Hu, J Cheung, Improved performance of lithium-ion cells with the use of fluorinated carbonate-based electrolytes Journal of Power Sources. ,vol. 119, pp. 359- 367 ,(2003) , 10.1016/S0378-7753(03)00266-0
Vladimír Cîrkva, Radek Polák, Oldřich Paleta, Radical additions to fluoroolefins. Photochemical fluoroalkylation of alkanols and alkane diols with perfluoro vinyl ethers; photo-supported O-alkylation of butane-1,4-diol with hexafluoropropene Journal of Fluorine Chemistry. ,vol. 80, pp. 135- 144 ,(1996) , 10.1016/S0022-1139(96)03514-2