Anomalous fluorescence and laser emission from 7-alkylamino coumarins in acid solutions

作者: R. Srinivasan , R.J. von Gutfeld , C.S. Angadiyavar , R.W. Dreyfus

DOI: 10.1016/0009-2614(74)85361-3

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摘要: Abstract The fluorescence emission from alcoholic solutions of 7-monoalkylamino-4-methyl coumarins shifts blue to blue-green on the addition acid. Fluorescence and excitation spectra measured at various concentrations show that with increasing concentration, a new peak appears which is source in presence It suggested this species dimer coumarin. analyses amplified streak camera indicate due transient excited species, consistent model based H + dimeric state.

参考文章(7)
Richard H. Goodwin, Frederick Kavanagh, The fluorescence of coumarin derivatives as a function of pH. II Archives of Biochemistry and Biophysics. ,vol. 36, pp. 442- 455 ,(1952) , 10.1016/0003-9861(52)90431-1
Charles E. Wheelock, The Fluorescence of Some Coumarins1 Journal of the American Chemical Society. ,vol. 81, pp. 1348- 1352 ,(1959) , 10.1021/JA01515A021
S. Rangaswami, T. R. Seshadri, A note on certain constitutional factors controlling visible fluorescence in compounds of the benzo-pyrone group Proceedings of the Indian Academy of Sciences - Section A. ,vol. 12, pp. 375- 380 ,(1940) , 10.1007/BF03172583
B. N. Mattoo, Absorption and fluorescence spectra of coumarins Transactions of the Faraday Society. ,vol. 52, pp. 1184- 1194 ,(1956) , 10.1039/TF9565201184
R. Srinivasan, New materials for flash-pumped organic lasers IEEE Journal of Quantum Electronics. ,vol. 5, pp. 552- 553 ,(1969) , 10.1109/JQE.1969.1075695
R. von Gutfeld, B. Welber, E. Tynan, Increased laser tunability by acidification of organic dyes IEEE Journal of Quantum Electronics. ,vol. 6, pp. 532- 533 ,(1970) , 10.1109/JQE.1970.1076516
A. Dienes, C. Shank, R. Kohn, Characteristics of the 4-methylumbelliferone laser dye IEEE Journal of Quantum Electronics. ,vol. 9, pp. 833- 843 ,(1973) , 10.1109/JQE.1973.1077744