摘要: Although attempts to model the electrical double layer are more than a century old there is still no satisfactory explanation for variety of phenomena observed. In last few years, as result advances in experimental techniques well development theoretical interest interphases, has been an attempt construct this region based firmly on molecular concepts. The present paper surveys some progress made direction towards solution seven problems which arise consideration layer.
springer.com
sci-hub.st 参考文章(50)
Georges Valette, Double layer on silver single crystal electrodes in contact with electrolytes having anions which are slightly specifically adsorbed Journal of Electroanalytical Chemistry and Interfacial Electrochemistry. ,vol. 138, pp. 37- 54 ,(1982) , 10.1016/0022-0728(82)87126-X
G. Valette, Double layer on silver single-crystal electrodes in contact with electrolytes having anions which present a slight specific adsorption Journal of Electroanalytical Chemistry. ,vol. 122, pp. 285- 297 ,(1981) , 10.1016/S0022-0728(81)80159-3
N. F. Mott, R. Parsons, R. J. Watts-Tobin, The capacity of a mercury electrode in electrolytic solution Philosophical Magazine. ,vol. 7, pp. 483- 493 ,(1962) , 10.1080/14786436208212180
M. V. Sangaranarayanan, S. K. Rangarajan, Microscopic modelling of adsorption and the generalised surface layer hypothesis Canadian Journal of Chemistry. ,vol. 59, pp. 2072- 2079 ,(1981) , 10.1139/V81-302
A. A. Kornyshev, W. Schmickler, M. A. Vorotyntsev, Nonlocal electrostatic approach to the problem of a double layer at a metal-electrolyte interface Physical Review B. ,vol. 25, pp. 5244- 5256 ,(1982) , 10.1103/PHYSREVB.25.5244
J.W. Schultze, F.D. Koppitz, Bond formation in electrosorbates—I correlation between the electrosorption valency and pauling's electronegativity for aqueous solutions☆ Electrochimica Acta. ,vol. 21, pp. 327- 336 ,(1976) , 10.1016/0013-4686(76)85022-0
H.H. Girault, D.J. Schiffrin, Thermodynamic surface excess of water and ionic solvation at the interface between immiscible liquids Journal of Electroanalytical Chemistry. ,vol. 150, pp. 43- 49 ,(1983) , 10.1016/S0022-0728(83)80188-0
L.M. Baugh, R. Parsons, The adsorption of amino acids at the mercury-water interphase Part I. Glycine in acid, neutral and base solutions Journal of Electroanalytical Chemistry and Interfacial Electrochemistry. ,vol. 41, pp. 311- 328 ,(1973) , 10.1016/S0022-0728(73)80445-0
J. Lipkowski, C. Nguyen Van Huong, C. Hinnen, R. Parsons, J. Chevalet, Adsorption of diethylether on single-crystal gold electrodes Journal of Electroanalytical Chemistry. ,vol. 143, pp. 375- 396 ,(1983) , 10.1016/S0022-0728(83)80275-7
Irwin Norman, J. N. Pitts, Structure and Reactivity in the Vapor Phase Photolysis of Ketones. III. Methyl Cyclobutyl Ketone1,2 Journal of the American Chemical Society. ,vol. 76, pp. 4815- 4819 ,(1954) , 10.1021/JA01628A003