Novel nanocomposite proton exchange membranes based on Nafion® and AMPS-modified montmorillonite for fuel cell applications
作者： Mohammad Mahdi Hasani-Sadrabadi , Erfan Dashtimoghadam , Fatemeh S Majedi , Kourosh Kabiri , Mehran Solati-Hashjin
DOI: 10.1016/J.MEMSCI.2010.09.014
关键词:
摘要: Abstract A series of novel proton exchange membranes based on Nafion ® and 2-acrylamido-2-methylpropanesulfonic acid (AMPS) modified montmorillonite (MMT) were prepared investigated for high performance fuel cell applications. X-ray diffraction patterns revealed an exfoliated microstructure the clay in matrices. Proton conductivity methanol permeability results indicated that incorporation AMPS-modified MMT into matrices considerably reduced crossover while maintaining properties. Direct methanol–air single tests a efficiency 20% /AMPS-MMT-3 wt.% compared to 13.72% 117 at 5 M feed, also higher power density 88 mW cm −2 39 mW cm 117. Owing such favorable features, fabricated /AMPS-MMT could be considered as promising polymeric electrolytes
elsevier.com
sci-hub.se 参考文章(33)
R.-Q. Fu, L. Hong, J.-Y. Lee, Membrane Design for Direct Ethanol Fuel Cells: A Hybrid Proton‐Conducting Interpenetrating Polymer Network Fuel Cells. ,vol. 8, pp. 52- 61 ,(2008) , 10.1002/FUCE.200700041
Min-Kyu Song, Seung-Bae Park, Young-Taek Kim, Ki-Hyun Kim, Sung-Kyu Min, Hee-Woo Rhee, Characterization of polymer-layered silicate nanocomposite membranes for direct methanol fuel cells Electrochimica Acta. ,vol. 50, pp. 639- 643 ,(2004) , 10.1016/J.ELECTACTA.2003.12.078
Klaus Schmidt-Rohr, Qiang Chen, Parallel cylindrical water nanochannels in Nafion fuel-cell membranes. Nature Materials. ,vol. 7, pp. 75- 83 ,(2008) , 10.1038/NMAT2074
Erfan Dashtimoghadam, Mohammad Mahdi Hasani-Sadrabadi, Homayoun Moaddel, Structural modification of chitosan biopolymer as a novel polyelectrolyte membrane for green power generation Polymers for Advanced Technologies. ,vol. 21, pp. 726- 734 ,(2010) , 10.1002/PAT.1496
Youngkwon Kim, Jae Sung Lee, Chang Houn Rhee, Hae Kyung Kim, Hyuk Chang, Montmorillonite functionalized with perfluorinated sulfonic acid for proton-conducting organic–inorganic composite membranes Journal of Power Sources. ,vol. 162, pp. 180- 185 ,(2006) , 10.1016/J.JPOWSOUR.2006.07.041
Tae Kyoung Kim, Myeongsoon Kang, Yeong Suk Choi, Hae Kyung Kim, Wonmok Lee, Hyuk Chang, Doyoung Seung, Preparation of Nafion-sulfonated clay nanocomposite membrane for direct menthol fuel cells via a film coating process Journal of Power Sources. ,vol. 165, pp. 1- 8 ,(2007) , 10.1016/J.JPOWSOUR.2006.11.055
Mohammad Mahdi Hasani-Sadrabadi, Erfan Dashtimoghadam, Fatemeh S Majedi, Kourosh Kabiri, Nassir Mokarram, Mehran Solati-Hashjin, Homayoun Moaddel, None, Novel high-performance nanohybrid polyelectrolyte membranes based on bio-functionalized montmorillonite for fuel cell applications Chemical Communications. ,vol. 46, pp. 6500- 6502 ,(2010) , 10.1039/C0CC01125H
Nagi Greesh, Patrice C. Hartmann, Valeska Cloete, Ronald D. Sanderson, Adsorption of 2-acrylamido-2-methyl-1-propanesulfonic acid (AMPS) and related compounds onto montmorillonite clay joint international conference on information sciences. ,vol. 319, pp. 2- 11 ,(2008) , 10.1016/J.JCIS.2007.10.019
Mohammad Mahdi Hasani-Sadrabadi, Shahriar Hojjati Emami, Homayoun Moaddel, Preparation and characterization of nanocomposite membranes made of poly(2,6-dimethyl-1,4-phenylene oxide) and montmorillonite for direct methanol fuel cells Journal of Power Sources. ,vol. 183, pp. 551- 556 ,(2008) , 10.1016/J.JPOWSOUR.2008.05.034
Rafael Herrera Alonso, Luis Estevez, Huiqin Lian, Antonios Kelarakis, Emmanuel P. Giannelis, Nafion–clay nanocomposite membranes: Morphology and properties Polymer. ,vol. 50, pp. 2402- 2410 ,(2009) , 10.1016/J.POLYMER.2009.03.020