Nitrobenzene preparation method
作者： Liu Yaling , Zou Pei , Wu Jun , Zhu Feifan , Xie Minhao
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摘要: The invention relates to a nitrobenzene preparation method. the method takes chlorobenzene as raw material, under existence of nitrating agent and copper catalyst, is reacted in an aprotic solvent; preferably, nitrite, catalyst complex formed by atoms and/or sub ions ligand; ligand organic amine one selected from alkali metal alkaline earth nitrite ammonium nitrite. has advantages wide material source, mild reaction condition, simple operation high yield, adapted industrial production.
lens.org 参考文章(6)
Boris Holm, Method of manufacturing o- and p-nitrobenzaldehyde ,(1985)
Thaddeus S. Franczyk, Vincent S. Chan, David M. Barnes, Travis B. Dunn, Shashank Shekhar, Anthony R. Haight, Phosphine ligands for catalytic reactions ,(2011)
Rhiannon Thomas, Amy E. Kallmerten, Graham B. Jones, Paul LaBeaume, Michael Placzek, Mathew Daniels, Ian Kendrick, Patrick Ng, Melissa McNeel, Roushan Afroze, Abigail Alexander, Microwave-accelerated fluorodenitrations and nitrodehalogenations: expeditious routes to labeled PET ligands and fluoropharmaceuticals Tetrahedron Letters. ,vol. 51, pp. 1906- 1909 ,(2010) , 10.1016/J.TETLET.2010.02.042
Seung-Uk Paik, Myoung-Geun Jung, Rapid Microwave-Assisted Copper-Catalyzed Nitration of Aromatic Halides with Nitrite Salts Bulletin of The Korean Chemical Society. ,vol. 33, pp. 689- 691 ,(2012) , 10.5012/BKCS.2012.33.2.689
Shinichi Saito, Yuichiro Koizumi, Copper-catalyzed coupling of aryl halides and nitrite salts: a mild Ullmann-type synthesis of aromatic nitro compounds Tetrahedron Letters. ,vol. 46, pp. 4715- 4717 ,(2005) , 10.1016/J.TETLET.2005.05.033
Feng Ke, Pan Jihong, Pi Jinhong, Yang Shangjin, Xie Guofan, Guo Yabing, Zhu Yi, Method for synthesizing chloramphenicol from nitromethane ,(2013)