Simultaneous formation of mono- and dications of free-base tetraphenylporphin during photo-oxidation probed by resonance Raman and absorption techniques
作者： G.S.S. Saini , O.K. Medhi , A.L. Verma
DOI: 10.1016/S0009-2614(00)00414-0
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摘要: Abstract We report the simultaneous formation of mono- and dication (known as diacid) radicals during photo-oxidation free-base tetraphenylporphin by selective laser excitations using resonance Raman optical absorption techniques. During process in carbon tetrachloride, addition even a small quantity tetrahydrofuran leads to along with monocation radical. A mechanism di- is proposed.
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