Determination of Cadmium (II) in Aqueous Solutions by In Situ MID-FTIR-PLS Analysis Using a Polymer Inclusion Membrane-Based Sensor: First Considerations
作者： René González-Albarrán , Josefina de Gyves , Eduardo Rodríguez de San Miguel
DOI: 10.3390/MOLECULES25153436
关键词:
摘要: Environmental monitoring is one of the most dynamically developing branches chemical analysis. In this area, use multidimensional techniques and methods encouraged to allow reliable determinations metal ions with portable equipment for in-field applications. regard, study presents, first time, capabilities a polymer inclusion membrane (PIM) sensor perform cadmium (II) determination in aqueous solutions by situ visible (VIS) Mid- Fourier transform infrared spectroscopy (MID-FTIR) analyses polymeric films, using partial least squares (PLS) chemometric approach. The influence pH content on extraction, characterization its extraction terms adsorption isotherm, enrichment factor equilibrium were studied. PLS algorithm was applied spectral data establish relationship between absorption spectra. Furthermore, developed MID-FTIR method validated through figures merit (accuracy, linearity, sensitivity, analytical minimum discernible concentration difference, mean selectivity, limits detection quantitation). Results showed calibration curves denoting systems’ potentiality. Comparable results obtained analysis real samples (tap, bottle, pier water) new MID-FTIR-PLS PIM based-sensor F-AAS.
mdpi.com
sci-hub.st 参考文章(58)
J Namiesnik, Modern trends in monitoring and analysis of environmental pollutants Polish Journal of Environmental Studies. ,vol. 10, ,(2001)
Daniela Saviello, Lucia Toniolo, Sara Goidanich, Francesca Casadio, Non-invasive identification of plastic materials in museum collections with portable FTIR reflectance spectroscopy: Reference database and practical applications Microchemical Journal. ,vol. 124, pp. 868- 877 ,(2016) , 10.1016/J.MICROC.2015.07.016
Jihui Li, Yan Zhang, Wensheng Cai, Xueguang Shao, Simultaneous determination of mercury, lead and cadmium ions in water using near-infrared spectroscopy with preconcentration by thiol-functionalized magnesium phyllosilicate clay. Talanta. ,vol. 84, pp. 679- 683 ,(2011) , 10.1016/J.TALANTA.2011.01.072
P. Vandenabeele, K. Castro, M. Hargreaves, L. Moens, J.M. Madariaga, H.G.M. Edwards, Comparative study of mobile Raman instrumentation for art analysis Analytica Chimica Acta. ,vol. 588, pp. 108- 116 ,(2007) , 10.1016/J.ACA.2007.01.082
Nan Sheng, Wensheng Cai, Xueguang Shao, An approach by using near-infrared diffuse reflectance spectroscopy and resin adsorption for the determination of copper, cobalt and nickel ions in dilute solution Talanta. ,vol. 79, pp. 339- 343 ,(2009) , 10.1016/J.TALANTA.2009.03.059
Jez Willian Batista Braga, Lilian Cristina Trevizan, Lidiane Cristina Nunes, Iolanda Aparecida Rufini, Dário Santos, Francisco José Krug, Comparison of univariate and multivariate calibration for the determination of micronutrients in pellets of plant materials by laser induced breakdown spectrometry Spectrochimica Acta Part B: Atomic Spectroscopy. ,vol. 65, pp. 66- 74 ,(2010) , 10.1016/J.SAB.2009.11.007
Hong Zheng, Donghong Liu, Yan Zheng, Shuping Liang, Zhe Liu, Sorption isotherm and kinetic modeling of aniline on Cr-bentonite. Journal of Hazardous Materials. ,vol. 167, pp. 141- 147 ,(2009) , 10.1016/J.JHAZMAT.2008.12.093
Rajesh Singh, Rout Chadetrik, Rajender Kumar, Kiran Bishnoi, Divya Bhatia, Anil Kumar, Narsi R Bishnoi, Namita Singh, None, Biosorption optimization of lead(II), cadmium(II) and copper(II) using response surface methodology and applicability in isotherms and thermodynamics modeling. Journal of Hazardous Materials. ,vol. 174, pp. 623- 634 ,(2010) , 10.1016/J.JHAZMAT.2009.09.097
Kenji Tsujikawa, Kenji Kuwayama, Hajime Miyaguchi, Tatsuyuki Kanamori, Yuko T. Iwata, Takemi Yoshida, Hiroyuki Inoue, Development of an on-site screening system for amphetamine-type stimulant tablets with a portable attenuated total reflection Fourier transform infrared spectrometer Analytica Chimica Acta. ,vol. 608, pp. 95- 103 ,(2008) , 10.1016/J.ACA.2007.12.002
Yan Zhang, Yong Hao, Wensheng Cai, Xueguang Shao, Simultaneous determination of phenol and p-nitrophenol in wastewater using near-infrared diffuse reflectance spectroscopy with adsorption preconcentration Analytical Methods. ,vol. 3, pp. 703- 708 ,(2011) , 10.1039/C0AY00775G