Quantum mechanical theory of molecular collisions in a laser field

作者: I. Harold Zimmerman , Jian‐Min Yuan , Thomas F. George

DOI: 10.1063/1.434264

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摘要: The effect of a radiation field on (ion)atom–(di)atom collision systems is considered. A detailed derivation presented for the modified coupled equations that result from adding to channel formalism nonreactive collisions. discussion coherent state in this context concludes number representation offers more convenient basis defining probability channels combined system, but further research applicability approximate treatments system should be carried out. An example general worked out collinear Br+H2 collisions presence field, and calculated results are presented. Comparison made with obtained vibronic (resonance) model.

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