Effects of compatibility of poly(l-lactic-acid) and thermoplastic polyurethane on mechanical property of blend fiber: EFFECTS OF COMPATIBILITY OF POLY AND THERMOPLASTIC POLYURETHANE
作者： Dan-Ying Zuo , Lei Zhang , Chang-Hai Yi , Han-Tao Zuo
DOI: 10.1002/PAT.3382
关键词:
摘要: Blending poly(l-lactic-acid) (PLLA) and thermoplastic polyurethane (TPU) has been performed in an effort to toughen PLLA without compromising its biodegradability biocompatibility. The mixing enthalpy calculation of TPU predicted that the blend was a thermodynamic miscible system. viscoelastic properties phase morphologies PLLA/TPU blends were investigated further by dynamic mechanical analysis scanning electron microscopy. It found partially showed Tg shifted toward with content increasing. Scanning microscopy photos changed from sea island structure bicontinuous as increment content, which suggested miscibility enhanced when increased. fibers fabricated. With increasing 0 wt% 30 wt%, tensile strength initial modulus decreased first then increased, while elongation at break fracture work gradually change indicated toughening effects on fibers, also formation influenced rheological behavior other than compatibility. Copyright © 2014 John Wiley & Sons, Ltd.
sci-hub.se 参考文章(24)
Tae Hwan Oh, Sung Soo Han, Won Seok Lyoo, Effect of polystyrene mixing on mechanical properties and structural changes in melt spinning Fibers and Polymers. ,vol. 11, pp. 1165- 1169 ,(2010) , 10.1007/S12221-010-1165-7
Caihong Diao, Changfa Xiao, Xiaoyu Hu, Xuemin Hu, Study on polyacrylonitrile fibers modified by blending with polyethylene glycol Fibers and Polymers. ,vol. 11, pp. 947- 951 ,(2010) , 10.1007/S12221-010-0947-2
J.E Robertson, T.C Ward, A.J Hill, Thermal, mechanical, physical, and transport properties of blends of novel oligomer and thermoplastic polysulfone Polymer. ,vol. 41, pp. 6251- 6262 ,(2000) , 10.1016/S0032-3861(99)00829-0
R. F. Storey, J. S. Wiggins, A. D. Puckett, Hydrolyzable poly(ester-urethane) networks from L-lysine diisocyanate and D,L-lactide/ε-caprolactone homo- and copolyester triols Journal of Polymer Science Part A: Polymer Chemistry. ,vol. 32, pp. 2345- 2363 ,(1994) , 10.1002/POLA.1994.080321216
Andrea Lucke, Jörg Teßmar, Edith Schnell, Georg Schmeer, Achim Göpferich, Biodegradable poly(d,l-lactic acid)-poly(ethylene glycol)-monomethyl ether diblock copolymers: structures and surface properties relevant to their use as biomaterials Biomaterials. ,vol. 21, pp. 2361- 2370 ,(2000) , 10.1016/S0142-9612(00)00103-4
Mitsuhiro Shibata, Yusuke Inoue, Masanao Miyoshi, Mechanical properties, morphology, and crystallization behavior of blends of poly(l-lactide) with poly(butylene succinate-co-l-lactate) and poly(butylene succinate) Polymer. ,vol. 47, pp. 3557- 3564 ,(2006) , 10.1016/J.POLYMER.2006.03.065
C. L. Simões, J. C. Viana, A. M. Cunha, Mechanical properties of poly(ε‐caprolactone) and poly(lactic acid) blends Journal of Applied Polymer Science. ,vol. 112, pp. 345- 352 ,(2009) , 10.1002/APP.29425
Naiwen Zhang, Qinfeng Wang, Jie Ren, Liang Wang, Preparation and properties of biodegradable poly(lactic acid)/poly(butylene adipate- co -terephthalate) blend with glycidyl methacrylate as reactive processing agent Journal of Materials Science. ,vol. 44, pp. 250- 256 ,(2009) , 10.1007/S10853-008-3049-4
A SIMMONS, J HYVARINEN, L POOLEWARREN, The effect of sterilisation on a poly(dimethylsiloxane)/poly(hexamethylene oxide) mixed macrodiol-based polyurethane elastomer Biomaterials. ,vol. 27, pp. 4484- 4497 ,(2006) , 10.1016/J.BIOMATERIALS.2006.04.017
Ping Huang, Sixun Zheng, Jinyu Huang, Qipeng Guo, Wei Zhu, Miscibility and mechanical properties of epoxy resin/polysulfone blends Polymer. ,vol. 38, pp. 5565- 5571 ,(1997) , 10.1016/S0032-3861(97)00104-3