Phthalide: a direct building-block towards P,O and P,N hemilabile ligands. Application in the palladium-catalysed Suzuki-Miyaura cross-coupling of aryl chlorides.
作者： James McNulty , Kunal Keskar
DOI: 10.1039/C3OB40198G
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摘要: The direct synthesis of new hemilabile ligands from the economical, readily available lactone phthalide is described. Pd-complexes one such ligand were found highly effective in general Suzuki–Miyaura cross-coupling reactions, including deactivated and hindered aryl chlorides.
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