SYNTHESIS OF 5-DODECANOYLAMINE-8-HYDROXY-1,4-NAPHTHOQUINONE AND STUDY OF SOME OF ITS BIVALENT METAL CHELATES

作者: M. Martinellp , V. Stefanp , A. E. Gerbase , M. Farias

DOI: 10.1080/00958979908023593

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摘要: Abstract Two new naphthoquinone derivatives, 5-dodecanoylamine-8-hydroxy-l,4-naphthoquinone (1) and 5-dodecanoylamine-8-acetoxy-l,4-naphthoquinone (2), have been prepared characterized. Their chelating ability with Ni(II) Co(II) studied. Compound coordinates to the divalent metal ions as a monoanionic bidentate ligand. The complexes were found contain two ligands molecules of coordinated water. structure bonding chelates are discussed based on spectroscopic data.

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