Multistate trajectory and statistical theories of spin-forbidden kinetics.

摘要: OH+ H2= H2O+ H 2.144 E8 1.52 3449. O+ OH= O2+ H 2.57 E13-0.1589-479.68 O+ H2= OH+ H 0.506 E+ 05 2.670 6290.000 H+ O2 (+ M)= HO2 (+ M) 5.8 E11 0.6724-290 LOW/7.2 E20-1.73 536/TROE/0.72 1E-30 1E30 1E30/AR/0.5/H2O/10/CO2/2/CH4/3/OH+ HO2= H2O+ O2 1.9 E16-1.0 0.0 H+ HO2= 2OH 1.69 E14 0.0 874. H+ HO2= H2+ O2 4.28 E13 0.0 1411. H+ HO2= O+ H2O 3.01 E13 0.0 1721. O+ HO2= O2+ OH 3.25 E13 0.0 0.0 2OH= O+ H2O 4.331 E3 2.7-2485.7 CH3+ OH= CH3OH 4.498 E8 1.3-54590C3H8+ C2H5= C3H7 (i)+ C2H6 1.51 E+ 00 3.46 7470.0 C3H8+ C2H5= C3H7 (n)+ C2H6 9.03 E-01 3.65 9140.0 C3H8+ CH2CHCH2= C3H6+ C3H7 (n) 2.35 E+ 02 3.3 19842.0 C3H8+ CH2CHCH2= C3H6+ C3H7 (i) 7.83 E+ 01 3.3 18169.0 C3H7 (n)(+ M)= C2H4+ CH3 (+ M) 1.23 E+ 13-0.1 30202.0