Large strain micromechanics of thermoplastic elastomers with random microstructures

摘要: Thermoplastic polyurethanes (TPU) are block copolymeric materials composed of plastomeric “hard” and elastomeric “soft” domains, by which they exhibit highly resilient yet dissipative large deformation features depending on volume fractions and microstructures of the two distinct domains. Here, we develop a new methodology to explore the microscopic deformation mechanisms in TPU materials with highly disordered microstructures. We propose new micromechanical models for randomly dispersed (or occluded) as well as randomly continuous hard domains (and mixtures of both dispersed and continuous hard domains), each within a continuous soft structure as widely found in representative TPU materials over a wide range of volume fractions, v hard= 26.9% to 52.2%. The micromechanical modeling results are compared to experimental data on the macroscopic large strain behaviors reported previously …