Unconventional hydrogen and dihydrogen bonded supramolecular array of a 2, 6-dioxa-9, 16-diaza-1, 3 (1, 2), 4 (1, 4)-tribenzenacycloheptadecaphane-borane adduct

摘要: The crystal structure of the title borane-oxaazacyclophane adduct consists of a tri-dimensional supramolecular array sustained by unconventional NH··· HB and CH··· HB dihydrogen bonding and weak CH··· π interactions. The interchain organization in the crystal structure is characterized by weak CH··· HB dihydrogen bonds.