The Structure of Tris (trifluoromethyl) tellurium Fluoride Dimethylformamide, \rmTe(CF_3)_3*DMF(μ-F)∞

摘要: Abstract \rmTe(CF_3)_3*DMF(μ-F)∞ represents the first structurally characterized example of a trifluoromethyl main group element compound with more than 8‐N (where N is the main group number) perfluoroalkyl groups and also the first fluoro (triorgano) tellurium derivative. Its polymeric nature is caused by asymmetric bridging fluorine atoms forming infinite chains.