Characterization of sol-gel derived PZT and PLZT thin films

作者: R. Kurchania , S.J. Milne

DOI: 10.1109/ISAF.1996.602785

关键词: DielectricTitanateAnalytical chemistryLanthanumLead zirconate titanateFerroelectricitySol-gelMaterials scienceThin filmSpin coating

摘要: Lead zirconate titanate (PZT) and lead lanthanum (PLZT) precursor sols were prepared using a diol based sol-gel route. Thin films deposited by spin coating onto PtrTi/SiO/sub 2//Si substrates. The effects of incorporating up to 10 mol% the base PZT 53/47 composition, firing temperature (500-700/spl deg/C) on crystallization, microstructure, ferroelectric dielectric properties have been investigated. Films fired at 700/spl deg/C for 15 minutes with 0, 2 5 mole percent levels had values remanent polarization 31, 23 14 /spl mu/C cm/sup -2/ (at 300 kV -1/, 60 Hz) corresponding relative permittivity 1485, 830 700 respectively.

参考文章(16)
Jie-Fang Li, Xunhu Dai, Albert Chow, Dwight Viehland, Polarization switching mechanisms and electromechanical properties of La-modified lead zirconate titanate ceramics Journal of Materials Research. ,vol. 10, pp. 926- 938 ,(1995) , 10.1557/JMR.1995.0926
Guanghua Yi, Zheng Wu, Michael Sayer, Preparation of Pb(Zr,Ti)O3 thin films by sol gel processing: Electrical, optical, and electro‐optic properties Journal of Applied Physics. ,vol. 64, pp. 2717- 2724 ,(1988) , 10.1063/1.341613
G. H. HAERTLING, C. E. LAND, Hot‐Pressed (Pb,La)(Zr,Ti)O3 Ferroelectric Ceramics for Electrooptic Applications Journal of the American Ceramic Society. ,vol. 54, pp. 1- 11 ,(1971) , 10.1111/J.1151-2916.1970.TB12105.X-I1
R. W. Vest, J. Xu, Preparation and properties of PLZT films from metallo-organic precursors Ferroelectrics. ,vol. 93, pp. 21- 29 ,(1989) , 10.1080/00150198908017316
Aaron B. Wegner, S. R. J. Brueck, A. Y. Wu, Integrated PLZT thin film waveguide modulators Ferroelectrics. ,vol. 116, pp. 195- 204 ,(1991) , 10.1080/00150199108007942
Radosveta D. Klissurska, Keith G. Brooks, Ian M. Reaney, Czezlaw Pawlaczyk, Marija Kosec, Nava Setter, Effect of Nb Doping on the Microstructure of Sol-Gel-Derived Pzt Thin-Films Journal of the American Ceramic Society. ,vol. 78, pp. 1513- 1520 ,(1995) , 10.1111/J.1151-2916.1995.TB08846.X
Takao Kawaguchi, Hideaki Adachi, Kentaro Setsune, Osamu Yamazaki, Kiyotaka Wasa, PLZT thin-film waveguides Applied Optics. ,vol. 23, pp. 2187- 2191 ,(1984) , 10.1364/AO.23.002187
M. Guglielmi, G. Carturan, Precursors for sol-gel preparations Journal of Non-crystalline Solids. ,vol. 100, pp. 16- 30 ,(1988) , 10.1016/0022-3093(88)90004-X
Jhing-Fang Chang, Seshu B. Desua, Effects of dopants in PZT films Journal of Materials Research. ,vol. 9, pp. 955- 969 ,(1994) , 10.1557/JMR.1994.0955