Solvent hydrolysis leads to an unusual Cu(ii) metal–organic framework
作者： Samuel M. Hawxwell , Lee Brammer
DOI: 10.1039/B603274E
关键词: Solvothermal synthesis 、 Inorganic chemistry 、 Polymer chemistry 、 Metal-organic framework 、 Dimethylamine 、 Chemistry 、 Hydrolysis 、 Solvent 、 Monoclinic crystal system 、 General Materials Science 、 General chemistry 、 Condensed matter physics
摘要: The two-dimensional metal–organic framework [Cu(terephthalate)(NHMe2)2] (1) has been prepared by solvothermal synthesis and characterised X-ray diffraction. [1, monoclinic, P21/c, a = 10.276(3), b 9.891(2), c 13.244(3) A, β 90.573(5)°, V 1346.1(6) A3, T 120(5) K, R1 0.065]. product arisen as result of hydrolysis reaction the DMF solvent. Compound 1 adopts compressed 44 network based upon dinuclear Cu2 nodes is unusual in containing coordinated dimethylamine ligands. propensity for consequences reactions such this are discussed.
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sci-hub.se 参考文章(31)
Jung Soo Seo, Dongmok Whang, Hyoyoung Lee, Sung Im Jun, Jinho Oh, Young Jin Jeon, Kimoon Kim, A homochiral metal-organic porous material for enantioselective separation and catalysis Nature. ,vol. 404, pp. 982- 986 ,(2000) , 10.1038/35010088
Makoto Fujita, Yoon Jung Kwon, Satoru Washizu, Katsuyuki Ogura, Preparation, Clathration Ability, and Catalysis of a Two-Dimensional Square Network Material Composed of Cadmium(II) and 4,4'-Bipyridine Journal of the American Chemical Society. ,vol. 116, pp. 1151- 1152 ,(1994) , 10.1021/JA00082A055
T. Hökelek, H. Necefouglu, Bis(μ‐4‐hydroxybenzoato‐O:O')bis[(N,N‐diethylnicotinamide‐N1)(4‐hydroxybenzoato‐O)zinc(II)] Dihydrate Acta Crystallographica Section C-crystal Structure Communications. ,vol. 52, pp. 1128- 1131 ,(1996) , 10.1107/S0108270195015976
Scott A. Hilderbrand, Stephen J. Lippard, Nitric Oxide Reactivity of Fluorophore Coordinated Carboxylate-Bridged Diiron(II) and Dicobalt(II) Complexes Inorganic Chemistry. ,vol. 43, pp. 5294- 5301 ,(2004) , 10.1021/IC049649L
S.V. Ganesan, Philip Lightfoot, Srinivasan Natarajan, A new zinc pyromellitate, [(C4N2H12)0.5(NH2(CH3)2][Zn(C10H2O8)]·1.78H2O, with a layered structure Solid State Sciences. ,vol. 6, pp. 757- 762 ,(2004) , 10.1016/J.SOLIDSTATESCIENCES.2004.03.032
Susumu Kitagawa, Ryo Kitaura, Shin-ichiro Noro, Functional Porous Coordination Polymers Angewandte Chemie International Edition. ,vol. 43, pp. 2334- 2375 ,(2004) , 10.1002/ANIE.200300610
Henrik Fanø Clausen, Rasmus Damgaard Poulsen, Andrew D. Bond, Marie-Agnes S. Chevallier, Bo Brummerstedt Iversen, Solvothermal synthesis of new metal organic framework structures in the zinc–terephthalic acid–dimethyl formamide system Journal of Solid State Chemistry. ,vol. 178, pp. 3342- 3351 ,(2005) , 10.1016/J.JSSC.2005.08.013
Jing Zhang, Yong-Rong Xie, Qiong Ye, Ren-Gen Xiong, Ziling Xue, Xiao-Zeng You, Blue to Red Fluorescent Emission Tuning of a Cadmium Coordination Polymer by Conjugated Ligands European Journal of Inorganic Chemistry. ,vol. 2003, pp. 2572- 2577 ,(2003) , 10.1002/EJIC.200300230
Mohamed Eddaoudi, Jaheon Kim, Nathaniel Rosi, David Vodak, Joseph Wachter, Michael O'Keeffe, Omar M Yaghi, Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage Science. ,vol. 295, pp. 469- 472 ,(2002) , 10.1126/SCIENCE.1067208
Andrew D. Burrows, Kevin Cassar, Richard M. W. Friend, Mary F. Mahon, Sean P. Rigby, John E. Warren, Solvent hydrolysis and templating effects in the synthesis of metal-organic frameworks CrystEngComm. ,vol. 7, pp. 548- 550 ,(2005) , 10.1039/B509460G