Synthesis and characterizations of three layered ZnII, CdII and MnII coordination polymers with a flexible ligand [3-(2-pyridyl)-1-pyrazolyl] acetic acid
作者： Lei Wang , Guang-Peng Jing , Pei Yang , Jing Chen
DOI: 10.1080/00958972.2015.1016006
关键词: Inorganic chemistry 、 Hydrolysis 、 Thermal stability 、 Isostructural 、 Chemistry 、 Acetic acid 、 Polymer 、 Crystallography 、 Coordination polymer 、 Carboxylate 、 Ligand
摘要: Self-assembly of flexible [3-(2-pyridyl)-1-pyrazolyl] acetic acid (Hpypza) with ZnCl2·4H2O, CdCl2·4H2O, and Mn(OAc)2·4H2O affords three new coordination polymers [M(pypza)(HCOO)]n (M = Zn for 1; Cd 2) [Mn(pypza)(OAc)]n (3), which are significantly different from the previously reported complexes [Zn(pypza)Cl]2, [Cd(pypza)Cl]n, [Mn(pypza)Cl]2, [Mn(pypza)Cl]n. These structural differences may be ascribed to use solvents anions. Single-crystal X-ray diffraction analyses these indicate that 1 2 isostructural a 2-D network via bridging pypza− HCOO− resulting hydrolysis DMF, 3 also displays connected OAc−. have been characterized by IR, microanalysis, powder techniques. In addition, solid fluorescence thermal stability properties 1–3 investigated. Magnetic MnII complex measured.
sci-hub.se 参考文章(38)
Miao Du, Cheng-Peng Li, Xiao-Jun Zhao, Qian Yu, Interplay of coordinative and supramolecular interactions in engineering unusual crystalline architectures of low-dimensional metal–pamoate complexes under co-ligand intervention CrystEngComm. ,vol. 9, pp. 1011- 1028 ,(2007) , 10.1039/B707853F
Samuel M. Hawxwell, Lee Brammer, Solvent hydrolysis leads to an unusual Cu(ii) metal–organic framework CrystEngComm. ,vol. 8, pp. 473- 476 ,(2006) , 10.1039/B603274E
Miao Du, Cheng-Peng Li, Jian-Hua Guo, Unusual anion effect on the direction of three-dimensional (3-D) channel-like silver(I) coordination frameworks with isonicotinic acid N-oxide CrystEngComm. ,vol. 11, pp. 1536- 1540 ,(2009) , 10.1039/B903074C
Qiao-Yun Li, Ming-Hua He, Zhen-Dong Shen, Gao-Wen Yang, Zhi-Yong Yuan, pH Dependent structural diversity of lead compounds based on new flexible ligand [3-(2-pyridyl)-1-pyrazolyl] acetic acid Inorganic Chemistry Communications. ,vol. 20, pp. 214- 218 ,(2012) , 10.1016/J.INOCHE.2012.03.011
Hua Cai, Ying Guo, Jian-Gang Li, Hydrothermal syntheses and characterization of a series of mixed-ligand luminescent CdII frameworks with novel 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl) acetate ligand and benzenedicarboxylate isomers Inorganic Chemistry Communications. ,vol. 34, pp. 37- 41 ,(2013) , 10.1016/J.INOCHE.2013.05.003
Wentong Chen, Shunichi Fukuzumi, Ligand-dependent ultrasonic-assistant self-assemblies and photophysical properties of lanthanide nicotinic/isonicotinic complexes. Inorganic Chemistry. ,vol. 48, pp. 3800- 3807 ,(2009) , 10.1021/IC9000279
Angel Gutiérrez, M Felisa Perpiñán, Ana E Sánchez, M Carmen Torralba, M Rosario Torres, M Pilar Pardo, None, Influence of the counter anion and solvent in the structure of copper derivatives with the 2,3-bis(2-pyridyl)pyrazine ligand Inorganica Chimica Acta. ,vol. 363, pp. 2443- 2451 ,(2010) , 10.1016/J.ICA.2010.03.080
Jie Yang, Lei Shen, Gao-Wen Yang, Qiao-Yun Li, Liu-Liu Zhu, Wei Shen, Cheng Ji, Xiao-Feng Shen, Four novel coordination compounds containing Hpypza ligand [Hpypza = [3-(2-pyridyl)-1-pyrazolyl] acetic acid] Inorganica Chimica Acta. ,vol. 392, pp. 25- 29 ,(2012) , 10.1016/J.ICA.2012.06.012
Ju-Hsiou Liao, Wan-Ting Chen, Cherng-Shiaw Tsai, Ching-Chun Yang, Chih-Chieh Wang, Synthesis, structure and hydrogen adsorption of a novel porous metal–organic framework, Mn9(btt)2(HCOO)12·0.7DMF·0.9H2O, where btt = 1,3,5-benzenetristetrazolate CrystEngComm. ,vol. 12, pp. 3033- 3037 ,(2010) , 10.1039/B925769A
Dong-Sheng Li, Long Tang, Feng Fu, Miao Du, Jun Zhao, Ni Wang, Peng Zhang, Coordination assemblies of CdII/ZnII/CoII with the 3-(pyridin-4-yl) benzoate tecton: Structural diversity and properties Inorganic Chemistry Communications. ,vol. 13, pp. 1126- 1130 ,(2010) , 10.1016/J.INOCHE.2010.06.023