Catalytic Hydrogen Evolution by Fe(II) Carbonyls Featuring a Dithiolate and a Chelating Phosphine

作者: Souvik Roy , Shobeir K. S. Mazinani , Thomas L. Groy , Lu Gan , Pilarisetty Tarakeshwar

DOI: 10.1021/IC5012988

关键词: Inorganic chemistryCrystal structureCrystallographyTrigonal bipyramidal molecular geometrySquare pyramidal molecular geometryActive sitePhosphineCatalysisElectrochemistryChemistryProtonation

摘要: … Two chelating phosphine ligands have been used to prepare complexes of the form (bdt)Fe(CO)P 2 [bdt = benzene-1,2-dithiolate; P 2 = 1,1′-diphenylphosphinoferrocene (1) or methyl-…

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