Formation, reactivity and redox properties of carbon- and sulfur-bridged diiron complexes derived from dibenzothienyl Schiff bases: effect of N,N- and N,P-chelating moieties
摘要: Redox properties of C,S-bridged diiron complexes were controlled by using dibenzothienyl Schiff base precursors with an N,N- or N,P-chelating moiety.
Petko Chernev, Camilla Lambertz, Annika Brünje, Nils Leidel, Kajsa G. V. Sigfridsson, Ramona Kositzki, Chung-Hung Hsieh, Shenglai Yao, Rafael Schiwon, Matthias Driess, Christian Limberg, Thomas Happe, Michael Haumann, Hydride binding to the active site of [FeFe]-hydrogenase.Inorganic Chemistry. ,vol. 53, pp. 12164- 12177 ,(2014) , 10.1021/IC502047Q