Formation, reactivity and redox properties of carbon- and sulfur-bridged diiron complexes derived from dibenzothienyl Schiff bases: effect of N,N- and N,P-chelating moieties

作者: Kiyokazu Santo , Masakazu Hirotsu , Isamu Kinoshita

DOI: 10.1039/C4DT03422H

关键词:

摘要: Redox properties of C,S-bridged diiron complexes were controlled by using dibenzothienyl Schiff base precursors with an N,N- or N,P-chelating moiety.

参考文章(42)
Matthew T. Olsen, Thomas B. Rauchfuss, Scott R. Wilson, Role of the azadithiolate cofactor in models for [FeFe]-hydrogenase: novel structures and catalytic implications. Journal of the American Chemical Society. ,vol. 132, pp. 17733- 17740 ,(2010) , 10.1021/JA103998V
James C. Lansing, James M. Camara, Danielle E. Gray, Thomas B. Rauchfuss, Hydrogen Production Catalyzed by Bidirectional, Biomimetic Models of the [FeFe]-Hydrogenase Active Site. Organometallics. ,vol. 33, pp. 5897- 5906 ,(2014) , 10.1021/OM5004013
Souvik Roy, Shobeir K. S. Mazinani, Thomas L. Groy, Lu Gan, Pilarisetty Tarakeshwar, Vladimiro Mujica, Anne K. Jones, Catalytic Hydrogen Evolution by Fe(II) Carbonyls Featuring a Dithiolate and a Chelating Phosphine Inorganic Chemistry. ,vol. 53, pp. 8919- 8929 ,(2014) , 10.1021/IC5012988
Petko Chernev, Camilla Lambertz, Annika Brünje, Nils Leidel, Kajsa G. V. Sigfridsson, Ramona Kositzki, Chung-Hung Hsieh, Shenglai Yao, Rafael Schiwon, Matthias Driess, Christian Limberg, Thomas Happe, Michael Haumann, Hydride binding to the active site of [FeFe]-hydrogenase. Inorganic Chemistry. ,vol. 53, pp. 12164- 12177 ,(2014) , 10.1021/IC502047Q
Masakazu Hirotsu, Kiyokazu Santo, Chiaki Tsuboi, Isamu Kinoshita, Diiron Carbonyl Complexes Bearing an N,C,S-Pincer Ligand: Reactivity toward Phosphines, Heterolytic Fe–Fe Cleavage, and Electrocatalytic Proton Reduction Organometallics. ,vol. 33, pp. 4260- 4268 ,(2014) , 10.1021/OM500558H
Daesung Chong, Irene P. Georgakaki, Rosario Mejia-Rodriguez, Jean Sanabria-Chinchilla, Manuel P. Soriaga, Marcetta Y. Darensbourg, Electrocatalysis of hydrogen production by active site analogues of the iron hydrogenase enzyme: structure/function relationships Dalton Transactions. pp. 4158- 4163 ,(2003) , 10.1039/B304283A
M. Y. Darensbourg, E. J. Lyon, X. Zhao, I. P. Georgakaki, The organometallic active site of [Fe]hydrogenase: models and entatic states. Proceedings of the National Academy of Sciences of the United States of America. ,vol. 100, pp. 3683- 3688 ,(2003) , 10.1073/PNAS.0536955100