Influence of CuO on the Structure and Piezoelectric Properties of the Alkaline Niobate‐Based Lead‐Free Ceramics
作者： Enzhu Li , Hirofumi Kakemoto , Satoshi Wada , Takaaki Tsurumi
DOI: 10.1111/J.1551-2916.2006.01465.X
关键词: Piezoelectricity 、 Perovskite (structure) 、 Ceramic 、 Phase (matter) 、 Tetragonal crystal system 、 Mineralogy 、 Electromechanical coupling 、 Composite material 、 Ion 、 Materials science
摘要: Recently, it was reported that the alkaline niobate-based (K,Na,Li)(Nb,Ta,Sb)O3 (LF4) perovskite ceramics showed excellent piezoelectric properties and have been regarded as a new candidate of lead-free materials. However, effects additives on property LF4 not studied intensively so far. In this study, effect CuO addition to investigated. The sample tetragonal phase at room temperature also second with low melt point. With 0.05 wt% added, Cu2+ firstly incorporated into A site, while higher amounts substituted B-site ions. CuO-doping changed “hard” improvement mechanical quality factor from 26 137 but d31 constant electromechanical coupling reduced drastically same time.
sci-hub.se 参考文章(11)
Evelyn Hollenstein, Matthew Davis, Dragan Damjanovic, Nava Setter, Piezoelectric properties of Li- and Ta-modified (K0.5Na0.5)NbO3 ceramics Applied Physics Letters. ,vol. 87, pp. 182905- ,(2005) , 10.1063/1.2123387
M. Matsubara, K. Kikuta, S. Hirano, Piezoelectric properties of (K0.5Na0.5)(Nb1−xTax)O3−K5.4CuTa10O29 ceramics Journal of Applied Physics. ,vol. 97, pp. 114105- ,(2005) , 10.1063/1.1926396
Bao-Jin Chu, Da-Ren Chen, Guo-Rong Li, Qing-Rui Yin, Electrical properties of Na1/2Bi1/2TiO3–BaTiO3 ceramics Journal of The European Ceramic Society. ,vol. 22, pp. 2115- 2121 ,(2002) , 10.1016/S0955-2219(02)00027-4
M. Kosec, D. Kolar, On activated sintering and electrical properties of NaKNbO3 Materials Research Bulletin. ,vol. 10, pp. 335- 339 ,(1975) , 10.1016/0025-5408(75)90002-1
Yasuyoshi Saito, Hisaaki Takao, Toshihiko Tani, Tatsuhiko Nonoyama, Kazumasa Takatori, Takahiko Homma, Toshiatsu Nagaya, Masaya Nakamura, Lead-free piezoceramics Nature. ,vol. 432, pp. 84- 87 ,(2004) , 10.1038/NATURE03028
Takaaki Tsurumi, Takashi Ichihara, Kiyoshi Asaga, Masaki Daimon, Admittance‐Curve‐Fitting Method for Semiconductive Piezoelectric Ceramics Journal of the American Ceramic Society. ,vol. 73, pp. 1330- 1333 ,(1990) , 10.1111/J.1151-2916.1990.TB05200.X
R. E. JAEGER, L. EGERTON, Hot Pressing of Potassium‐Sodium Niobates Journal of the American Ceramic Society. ,vol. 45, pp. 209- 213 ,(1962) , 10.1111/J.1151-2916.1962.TB11127.X
L. EGERTON, DOLORES M. DILLON, Piezoelectric and Dielectric Properties of Ceramics in the System Potassium—Sodium Niobate Journal of the American Ceramic Society. ,vol. 42, pp. 438- 442 ,(1959) , 10.1111/J.1151-2916.1959.TB12971.X
Masato Matsubara, Toshiaki Yamaguchi, Wataru Sakamoto, Koichi Kikuta, Toshinobu Yogo, Shin-ichi Hirano, Processing and Piezoelectric Properties of Lead‐Free (K,Na) (Nb,Ta) O3 Ceramics Journal of the American Ceramic Society. ,vol. 88, pp. 1190- 1196 ,(2005) , 10.1111/J.1551-2916.2005.00229.X
Tadashi Takenaka, Kei-ichi Maruyama, Koichiro Sakata, (Bi1/2Na1/2)TiO3-BaTiO3System for Lead-Free Piezoelectric Ceramics Japanese Journal of Applied Physics. ,vol. 30, pp. 2236- 2239 ,(1991) , 10.1143/JJAP.30.2236