Simultaneous measurements of complex heat capacity and complex thermal conductivity by two-channel AC calorimeter

作者: A.A. Minakov , S.A. Adamovsky , C. Schick

DOI: 10.1016/S0040-6031(01)00552-4

关键词: Thermal analysisThermodynamicsThermal diffusivityThermal transmittanceThermal effusivityThermal contact conductanceThermal resistanceChemistryThermal conductionThermal conductivity

摘要: The new capabilities of the advanced two-channel AC calorimetry, when working at frequencies above quasi-static limit, were shown. idea method was to use information about phases and amplitudes temperature oscillations on both sides a plate-like sample for direct simultaneous determination complex heat capacity C(ω) thermal conductivity λ(ω), measured sample. Therefore, complete set parameters can be in same experiment. provides possibility answer fundamental question value imaginary part conductivity. It found, that argument is considerably small with respect capacity. Thus, least within error experiment glass transition glycerol considered as real valued parameter. In spite strong frequency dependence capacity, no dependency observed.

参考文章(31)
C. Schick, M. Merzlyakov, A. Minakov, A. Wurm, Crystallization of polymers studied by temperature modulated calorimetric measurements at different frequencies Journal of Thermal Analysis and Calorimetry. ,vol. 59, pp. 279- 288 ,(2000) , 10.1023/A:1010108617592
B. Schiener, R. V. Chamberlin, G. Diezemann, R. Böhmer, Nonresonant dielectric hole burning spectroscopy of supercooled liquids Journal of Chemical Physics. ,vol. 107, pp. 7746- 7761 ,(1997) , 10.1063/1.475089
Alexander A. Minakov, Thermal contact conductance in advanced AC calorimetry Thermochimica Acta. ,vol. 345, pp. 3- 12 ,(2000) , 10.1016/S0040-6031(99)00360-3
P Claudy, J.C Commerçon, J.M Lètoffé, Quasi-static study of the glass transition of glycerol by DSC Thermochimica Acta. ,vol. 128, pp. 251- 260 ,(1988) , 10.1016/0040-6031(88)85369-3
David G. Cahill, R. O. Pohl, Thermal conductivity of amorphous solids above the plateau. Physical Review B. ,vol. 35, pp. 4067- 4073 ,(1987) , 10.1103/PHYSREVB.35.4067
A.A. Minakov, Yu.V. Bugoslavsky, C. Schick, Dynamic heat capacity measurements in advanced AC calorimetry Thermochimica Acta. ,vol. 342, pp. 7- 18 ,(1999) , 10.1016/S0040-6031(99)00298-1
A.A Minakov, C Schick, Advanced AC calorimetry of polycaprolactone in melting region Thermochimica Acta. ,vol. 330, pp. 109- 119 ,(1999) , 10.1016/S0040-6031(99)00025-8
N. Menon, Kevin P. O'Brien, Paul K. Dixon, Lei Wu, Sidney R. Nagel, Bruce D. Williams, John. P. Carini, Wide-frequency dielectric susceptibility measurements in glycerol Journal of Non-Crystalline Solids. ,vol. 141, pp. 61- 65 ,(1992) , 10.1016/S0022-3093(05)80519-8
Norman O. Birge, Sidney R. Nagel, Specific-Heat Spectroscopy of the Glass Transition Physical Review Letters. ,vol. 54, pp. 2674- 2677 ,(1985) , 10.1103/PHYSREVLETT.54.2674