Quasi-static study of the glass transition of glycerol by DSC
作者： P Claudy , J.C Commerçon , J.M Lètoffé
DOI: 10.1016/0040-6031(88)85369-3
关键词:
摘要: Abstract The glass transition of glycerol has been studied using a DSC apparatus in step heating mode, on cooling and warming. Using the electrical model calorimeter, supposed thermal behavior sample is computed, compared with experimental results. appears to be reversible, slow endothermic effect (5 J g−1) change capacity.
elsevier.com
sci-hub.se 参考文章(12)
W. O. Lundberg, J. E. Ahlberg, E. R. Blanchard, The Heat Capacities of Benzene, Methyl Alcohol and Glycerol at Very Low Temperatures The Journal of Chemical Physics. ,vol. 5, pp. 539- 551 ,(1937) , 10.1063/1.1750072
P. Claudy, J.C. Commercon, J.M Letoffe, Heat transfer in a disc-type DSC apparatus. III. Theoretical and experimental correction of the calorimetric signal in scanning mode Thermochimica Acta. ,vol. 68, pp. 317- 327 ,(1983) , 10.1016/0040-6031(83)80234-2
D.B Downie, J.F Martin, An adiabatic calorimeter for heat-capacity measurements between 6 and 300 K. The molar heat capacity of aluminium The Journal of Chemical Thermodynamics. ,vol. 12, pp. 779- 786 ,(1980) , 10.1016/0021-9614(80)90176-7
P. Claudy, J.C. Commercon, J.M. Letoffe, Heat transfer in a disc-type DSC apparatus. II. Theoretical representation Thermochimica Acta. ,vol. 68, pp. 305- 316 ,(1983) , 10.1016/0040-6031(83)80233-0
Heiner. Staub, Werner. Perron, New method of purity determination by means of calorimetric differential thermal analysis Analytical Chemistry. ,vol. 46, pp. 128- 130 ,(1974) , 10.1021/AC60337A039
A. G. Oblad, Roy F. Newton, The Heat Capacity of Supercooled Liquid Glycerol1 Journal of the American Chemical Society. ,vol. 59, pp. 2495- 2499 ,(1937) , 10.1021/JA01291A004
P. Claudy, B. Bonnetot, G. Chahine, J.M. Letoffe, Etude du comportement thermique du tetrahydroaluminate de sodium NaAlH4 et de l'hexahydroaluminate de sodium Na3AlH6 DE 298 A 600 K Thermochimica Acta. ,vol. 38, pp. 75- 88 ,(1980) , 10.1016/0040-6031(80)87150-4
L. Boehm, M.D. Ingram, C.A. Angell, Test of a year-annealed glass for the cohen-grest percolation transition Journal of Non-crystalline Solids. ,vol. 44, pp. 305- 313 ,(1981) , 10.1016/0022-3093(81)90033-8
S.C Mraw, D.F Naas, The measurement of accurate heat capacities by differential scanning calorimetry Comparison of d.s.c. results on pyrite (100 to 800 K) with literature values from precision adiabatic calorimetry The Journal of Chemical Thermodynamics. ,vol. 11, pp. 567- 584 ,(1979) , 10.1016/0021-9614(79)90097-1
A. A. Schaerer, C. J. Busso, A. E. Smith, L. B. Skinner, Properties of Pure Normal Alkanes in the C17 to C36 Range Journal of the American Chemical Society. ,vol. 77, pp. 2017- 2019 ,(1955) , 10.1021/JA01612A097