Analysis of Block and Statistical Copolymers by Gel Permeation Chromatography: Estimation of Mark-Houwink Constants

作者: J. M. Goldwasser , A. Rudin

DOI: 10.1080/01483918308064915

关键词: Copolymer compositionPolymerCopolymerGel permeation chromatographyChromatographyChemistryBlock (periodic table)Mark–Houwink equation

摘要: Abstract A method is introduced for the estimation of Mark-Houwink constants block and statistical copolymers. The homopolymer copolymer composition are required. Use estimated in GPC analyses gives results which agree well with those calculated experimentally determined constants. Comparisons between this Runyon coworkers (11) Chang (12) made Chang's was also extended to copolymers, where it compared closely one here. use as a qualitative measure polymer compatibilities different solvents discussed.

参考文章(33)
Anastasios Dondos, Paul Rempp, Henri Benoîct, Gel permeation chromatographic investigations on random and block copolymers Macromolecular Chemistry and Physics. ,vol. 175, pp. 1659- 1663 ,(1974) , 10.1002/MACP.1974.021750524
Paul J. Flory, Principles of polymer chemistry ,(1953)
Par Anastasios Dondos, Henri Benoît, Influence de la nature du solvant et de la température sur les dimensions non perturbées des copolymères statistiques PS–PMM Macromolecular Chemistry and Physics. ,vol. 118, pp. 165- 176 ,(1968) , 10.1002/MACP.1968.021180111
Anastasios Dondos, Paul Rempp, Henri Benoît, Investigations on conformations of block and of random copolymers in dilute solution Macromolecular Chemistry and Physics. ,vol. 130, pp. 233- 242 ,(1969) , 10.1002/MACP.1969.021300114
Alfred Rudin, R. A. Wagner, Solvent and concentration dependence of hydrodynamic volumes and GPC elution volumes Journal of Applied Polymer Science. ,vol. 20, pp. 1483- 1490 ,(1976) , 10.1002/APP.1976.070200607
E. P. Goldberg, E. J. Powers, Polycarbonate‐siloxy copolymers and blends Journal of Polymer Science Part B: Polymer Letters. ,vol. 2, pp. 835- 838 ,(1964) , 10.1002/POL.1964.110020818
Tadao Kotaka, Yoji Murakami, Hiroshi Inagaki, Dilute solution properties of styrene-methyl methacrylate random copolymers The Journal of Physical Chemistry. ,vol. 72, pp. 829- 841 ,(1968) , 10.1021/J100849A011
Sonja Krause, Dilute Solution Properties of a Styrene—Methyl Methacrylate Block Copolymer The Journal of Physical Chemistry. ,vol. 68, pp. 1948- 1955 ,(1964) , 10.1021/J100789A046
J. Bischoff, V. Desreux, Etude des solutions diluées de polyméthacrylate de méthyle I Bulletin des Sociétés Chimiques Belges. ,vol. 61, pp. 10- 32 ,(2010) , 10.1002/BSCB.19520610103