Observation of body centered cubic Cu in Cu/Nb nanolayered composites

作者: H. Kung , Y-C. Lu , A. J. Griffin , M. Nastasi , T. E. Mitchell

DOI: 10.1063/1.119611

关键词: Transmission electron microscopyTexture (crystalline)Cubic crystal systemFermi levelCrystal structurePhase (matter)CrystallographyFermi energyElectron energy loss spectroscopyMaterials science

摘要: The deposition of thin alternating layers Cu and Nb on Si(100) substrates has been studied by transmission electron microscopy as a function layer thickness. For thickness above 25 A, there is strong texture orientation relationship with the close packed planes fcc parallel to bcc Nb, forming so-called “Kurdjumov-Sachs” relationship. However, at thicknesses under 12 constrained grow slightly distorted structure. It thought that, when it reaches critical between 20 loses coherency transforms martensitically phase, resulting in observed Kurdjumov–Sachs Electron energy loss spectroscopy observations indicate difference 2 eV L3 edge suggesting that Fermi lower form than equilibrium

参考文章(13)
C. Schmidt, F. Ernst, M. W. Finnis, V. Vitek, Prediction and observation of the bcc structure in pure copper at a Sigma 3 grain boundary. Physical Review Letters. ,vol. 75, pp. 2160- 2163 ,(1995) , 10.1103/PHYSREVLETT.75.2160
W.A Spitzig, A.R. Pelton, F.C. Laabs, Characterization of the strength and microstructure of heavily cold worked CuNb composites Acta Metallurgica. ,vol. 35, pp. 2427- 2442 ,(1987) , 10.1016/0001-6160(87)90140-4
Ray F. Egerton, Dale E. Newbury, Electron Energy-Loss Spectroscopy in the Electron Microscope ,(1995)
M. El-Batanouny, Myron Strongin, Structural and electronic trends in the growth of Cu overlayers on the Nb(110) surface Physical Review B. ,vol. 31, pp. 4798- 4801 ,(1985) , 10.1103/PHYSREVB.31.4798
J. D. Verhoeven, H. L. Downing, L. S. Chumbley, E. D. Gibson, The resistivity and microstructure of heavily drawn Cu‐Nb alloys Journal of Applied Physics. ,vol. 65, pp. 1293- 1301 ,(1989) , 10.1063/1.343024
D. Van Heerden, D. Josell, D. Shechtman, The formation of f.c.c. titanium in titanium-aluminum multilayers Acta Materialia. ,vol. 44, pp. 297- 306 ,(1996) , 10.1016/1359-6454(95)00159-5
H. Li, S. C. Wu, D. Tian, J. Quinn, Y. S. Li, F. Jona, P. M. Marcus, Epitaxial growth of body-centered-tetragonal copper Physical Review B. ,vol. 40, pp. 5841- 5844 ,(1989) , 10.1103/PHYSREVB.40.5841
H. Li, D. Tian, J. Quinn, Y. S. Li, F. Jona, P. M. Marcus, Low-energy electron diffraction and photoemission study of epitaxial films of Cu on Ag{001} Physical Review B. ,vol. 43, pp. 6342- 6346 ,(1991) , 10.1103/PHYSREVB.43.6342
Rajarshi Banerjee, Rajiv Ahuja, Hamish L. Fraser, Dimensionally induced structural transformations in titanium-aluminum multilayers. Physical Review Letters. ,vol. 76, pp. 3778- 3781 ,(1996) , 10.1103/PHYSREVLETT.76.3778