Intramolecular vibrational redistribution in the S1 state of p-fluorotoluene
作者： D.A. Dolson , C.S. Parmenter , B.M. Stone
DOI: 10.1016/0009-2614(81)80269-2
关键词: Chemistry 、 Redistribution (chemistry) 、 Picosecond 、 Time evolution 、 Excitation 、 Atomic physics 、 Fluorescence spectra 、 Intramolecular force 、 Physical and Theoretical Chemistry 、 General Physics and Astronomy
摘要: Abstract Vibrational redistribution in S1p-fluorotoluene vapor has been observed by the picosecond time evolution of S1 → So fluorescence spectra after excitation an level with ϵvib = 1988 cm−1. The decay this is easily throughout first 50 ps. Rotational levels appear to be important participants redistribution.
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