Intrastate scrambling in a bound level structure of large molecules
作者： A Amirav , U Even , Joshua Jortner , None
DOI: 10.1016/0009-2614(80)85280-8
关键词: Supersonic speed 、 Mixing (physics) 、 Level structure 、 Scrambling 、 Anharmonicity 、 Vibrational energy 、 Chemistry 、 Tetracene 、 Molecule 、 Atomic physics 、 Physical and Theoretical Chemistry 、 General Physics and Astronomy
摘要: Abstract We advance a spectroscopic method for the identification of threshold intrastate anharinonic mixing in bound level structure large molecules, which rests on observation band splitting energy-resolved fluorescence spectra isolated molecule seeded supersonic beams. The anharmonic S1 state tetracene is exhibited at excess vibrational energy EV ≈ 1000 cm−1, below onset vibration quasicontinuum, occurs 1800 cm−1.
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B. Soep, A. Tramer, Fluorescence of glyoxal in supersonic jets Chemical Physics Letters. ,vol. 64, pp. 465- 468 ,(1979) , 10.1016/0009-2614(79)80223-7
A Amirav, U Even, Joshua Jortner, None, Spectroscopic identification of the onset of the vibrational quasicontinuum in large molecules Optics Communications. ,vol. 32, pp. 266- 268 ,(1980) , 10.1016/0030-4018(80)90121-2
Fred M. Behlen, Naohiko Mikami, Stuart A. Rice, Dynamics of radiationless processes studied in pulsed supersonic free jets: Some naphthalene lifetimes Chemical Physics Letters. ,vol. 60, pp. 364- 367 ,(1979) , 10.1016/0009-2614(79)80589-8
Izhack Oref, B. Seymour Rabinovitch, Do highly excited reactive polyatomic molecules behave ergodically Accounts of Chemical Research. ,vol. 12, pp. 166- 175 ,(1979) , 10.1021/AR50137A002
A Amirav, U Even, Joshua Jortner, None, Intramolecular dynamics of an isolated ultracold large molecule Journal of Chemical Physics. ,vol. 71, pp. 2319- 2321 ,(1979) , 10.1063/1.438569
Pamela S. H. Fitch, Lennard Wharton, Donald H. Levy, The fluorescence excitation spectrum of free base phthalocyanine cooled in a supersonic expansion Journal of Chemical Physics. ,vol. 69, pp. 3424- 3426 ,(1978) , 10.1063/1.436950
A Amirav, U Even, Joshua Jortner, None, Intermediate level structure in the s2 state of the isolated ultracold ovalene molecule Chemical Physics Letters. ,vol. 69, pp. 14- 17 ,(1980) , 10.1016/0009-2614(80)80003-0
S. M. Beck, M. G. Liverman, D. L. Monts, R. E. Smalley, Rotational analysis of the 1B2u(ππ) ←1A1g, (610) band of benzene and helium–benzene van der Waals complexes in a supersonic jet Journal of Chemical Physics. ,vol. 70, pp. 232- 237 ,(1979) , 10.1063/1.437237
Nicolaas Bloembergen, Eli Yablonovitch, Infrared‐laser‐induced unimolecular reactions Physics Today. ,vol. 31, pp. 23- 30 ,(1978) , 10.1063/1.2995035
Shaul Mukamel, Joshua Jortner, Multiphoton molecular dissociation in intense laser fields Journal of Chemical Physics. ,vol. 65, pp. 5204- 5225 ,(1976) , 10.1063/1.433073