Fluorreiche Fluoride – neue Erkenntnisse über die Chemie von Polyfluoridanionen
作者： Thomas Vent-Schmidt , Felix Brosi , Jens Metzger , Tobias Schlöder , Xuefeng Wang
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摘要: Polyfluoride wurden mittels Matrixisolationsspektroskopie und quantenchemischen Berechnungen auf Coupled-Cluster-Niveau untersucht. Erstmalig konnte ein hoheres Polyfluoridanion spektroskopisch in Neonmatrices bei 4 K nachgewiesen werden. Das C2v-symmetrische [F5]− weist eine sehr starke Bande 850 cm−1 auf. Daruber hinaus wird neue fur den Cs+[F3]−-Komplex Neon beschrieben.
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