Structural Proof for the First Dianion of a Polychloride: Investigation of [Cl8]2−
作者： Robin Brückner , Patrick Pröhm , Anja Wiesner , Simon Steinhauer , Carsten Müller
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摘要: The polychloride salt [CCl(NMe2 )2 ](+) 2 [Cl8 ](2-) was synthesized and crystallized in the ionic liquid [BMP]OTf. compound fully characterized by Raman spectroscopy as well X-ray single-crystal structure determination, represents first example of a dianion to be described. Detailed gas-phase solid-state calculations concerning nature bonding situation were also performed.
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