Bromine-rich complexes of bismuth: experimental and theoretical studies
作者： Sergey A. Adonin , Igor D. Gorokh , Alexander S. Novikov , Denis G. Samsonenko , Pavel E. Plyusnin
DOI: 10.1039/C7DT04779G
关键词:
摘要: Three novel polybromide complexes of bismuth(III) – (2,6-MePyH)3[BiBr5(Br3)] (1), (H2bpp){[BiBr5](Br2)} (2) and (3-ClPyH)2{[BiBr5](Br2)} (3) were synthesized. The results an extended screening involving a set organic cations resulting in the formation/non-formation Bi(III) polybromides are presented discussed. nature Br⋯Br interactions was investigated by theoretical methods, enabling estimation their energies.
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